Dichloridobis[5-nitro-1-trimethyl­silyl­methyl-1H-benzimidazole-κN (3)]cobalt(II) N,N-dimethyl­formamide solvate

The title compound, [CoCl(2)(C(11)H(15)N(3)O(2)Si)(2)]·C(3)H(7)NO, was synthesized from 5-nitro-1-trimethyl­silylmethyl-1H-benzimid­azole and cobalt(II) chloride in dimethyl­formamide. The Co(II) atom is coordinated in a distorted tetra­hedral environment by two Cl atoms and two N atoms. In the crys...

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Detalles Bibliográficos
Autores principales: Akkurt, Mehmet, Yalçın, Şerife Pınar, Şireci, Nihat, Küçükbay, Hasan, Tahir, M. Nawaz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983604/
https://www.ncbi.nlm.nih.gov/pubmed/21580208
http://dx.doi.org/10.1107/S1600536810003922
Descripción
Sumario:The title compound, [CoCl(2)(C(11)H(15)N(3)O(2)Si)(2)]·C(3)H(7)NO, was synthesized from 5-nitro-1-trimethyl­silylmethyl-1H-benzimid­azole and cobalt(II) chloride in dimethyl­formamide. The Co(II) atom is coordinated in a distorted tetra­hedral environment by two Cl atoms and two N atoms. In the crystal structure, there are a number of C—H⋯Cl and C—H⋯O hydrogen-bonding inter­actions between symmetry-related mol­ecules.

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