Hexakis(acetonitrile-κN)ruthenium(II) bis­(hexa­bromo­carbadodeca­borate) aceto­nitrile solvate

The title compound, [Ru(NCCH(3))(6)](CH(6)B(11)Br(6))(2)·CH(3)CN, consists of the ’naked’ ruthenium(II) cation surrounded by six acetonitrile mol­ecules, each coordinated via the nitro­gen atoms in a linear or nearly-linear fashion in a typical octa­hedral over-all arrangement. The cation is balance...

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Detalles Bibliográficos
Autores principales: Masland, Joshua, Diaz, Jason, Eady, Shawn, Lobkovsky, Emil, Larsen, Anna
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983605/
https://www.ncbi.nlm.nih.gov/pubmed/21580262
http://dx.doi.org/10.1107/S1600536810006252
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author Masland, Joshua
Diaz, Jason
Eady, Shawn
Lobkovsky, Emil
Larsen, Anna
author_facet Masland, Joshua
Diaz, Jason
Eady, Shawn
Lobkovsky, Emil
Larsen, Anna
author_sort Masland, Joshua
collection PubMed
description The title compound, [Ru(NCCH(3))(6)](CH(6)B(11)Br(6))(2)·CH(3)CN, consists of the ’naked’ ruthenium(II) cation surrounded by six acetonitrile mol­ecules, each coordinated via the nitro­gen atoms in a linear or nearly-linear fashion in a typical octa­hedral over-all arrangement. The cation is balanced by the two hexa-bromo­carborane cage anionic fragments [CB(11)H(6)Br(6)]. Weak C—H⋯Br and B—H⋯Br inter­actions link neighboring anions.
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spelling pubmed-29836052010-12-30 Hexakis(acetonitrile-κN)ruthenium(II) bis­(hexa­bromo­carbadodeca­borate) aceto­nitrile solvate Masland, Joshua Diaz, Jason Eady, Shawn Lobkovsky, Emil Larsen, Anna Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ru(NCCH(3))(6)](CH(6)B(11)Br(6))(2)·CH(3)CN, consists of the ’naked’ ruthenium(II) cation surrounded by six acetonitrile mol­ecules, each coordinated via the nitro­gen atoms in a linear or nearly-linear fashion in a typical octa­hedral over-all arrangement. The cation is balanced by the two hexa-bromo­carborane cage anionic fragments [CB(11)H(6)Br(6)]. Weak C—H⋯Br and B—H⋯Br inter­actions link neighboring anions. International Union of Crystallography 2010-02-24 /pmc/articles/PMC2983605/ /pubmed/21580262 http://dx.doi.org/10.1107/S1600536810006252 Text en © Masland et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Masland, Joshua
Diaz, Jason
Eady, Shawn
Lobkovsky, Emil
Larsen, Anna
Hexakis(acetonitrile-κN)ruthenium(II) bis­(hexa­bromo­carbadodeca­borate) aceto­nitrile solvate
title Hexakis(acetonitrile-κN)ruthenium(II) bis­(hexa­bromo­carbadodeca­borate) aceto­nitrile solvate
title_full Hexakis(acetonitrile-κN)ruthenium(II) bis­(hexa­bromo­carbadodeca­borate) aceto­nitrile solvate
title_fullStr Hexakis(acetonitrile-κN)ruthenium(II) bis­(hexa­bromo­carbadodeca­borate) aceto­nitrile solvate
title_full_unstemmed Hexakis(acetonitrile-κN)ruthenium(II) bis­(hexa­bromo­carbadodeca­borate) aceto­nitrile solvate
title_short Hexakis(acetonitrile-κN)ruthenium(II) bis­(hexa­bromo­carbadodeca­borate) aceto­nitrile solvate
title_sort hexakis(acetonitrile-κn)ruthenium(ii) bis­(hexa­bromo­carbadodeca­borate) aceto­nitrile solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983605/
https://www.ncbi.nlm.nih.gov/pubmed/21580262
http://dx.doi.org/10.1107/S1600536810006252
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