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Bis(N-{bis­[meth­yl(phen­yl)amino]phos­phor­yl}-2,2,2-trichloro­acetamide)di­nitrato­dioxidouranium(VI)

In the title compound, [UO(2) L (2)(NO(3))(2)] {L = N-{bis­[meth­yl(phen­yl)amino]phosphor­yl}-2,2,2-trichloro­acetamide, C(16)H(17)Cl(3)N(3)O(2)P}, the U(VI) ions are eight-coordinated by axial oxido ligands and six equatorial O atoms from the phosphoryl and nitrate groups in a distorted hexa­gonal...

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Autores principales: Znovjyak, Kateryna O., Ovchynnikov, Vladimir A., Sliva, Tetyana Yu., Shishkina, Svitlana V., Amirkhanov, Vladimir M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983606/
https://www.ncbi.nlm.nih.gov/pubmed/21580248
http://dx.doi.org/10.1107/S1600536810005611
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author Znovjyak, Kateryna O.
Ovchynnikov, Vladimir A.
Sliva, Tetyana Yu.
Shishkina, Svitlana V.
Amirkhanov, Vladimir M.
author_facet Znovjyak, Kateryna O.
Ovchynnikov, Vladimir A.
Sliva, Tetyana Yu.
Shishkina, Svitlana V.
Amirkhanov, Vladimir M.
author_sort Znovjyak, Kateryna O.
collection PubMed
description In the title compound, [UO(2) L (2)(NO(3))(2)] {L = N-{bis­[meth­yl(phen­yl)amino]phosphor­yl}-2,2,2-trichloro­acetamide, C(16)H(17)Cl(3)N(3)O(2)P}, the U(VI) ions are eight-coordinated by axial oxido ligands and six equatorial O atoms from the phosphoryl and nitrate groups in a distorted hexa­gonal–bipyramidal geometry. There are disordered fragments in the two coordinating L ligands: the trichloro­methyl group is rotationally disordered between two orientations [occupancy ratio 0.567 (15):0.433 (15)] in one ligand, and a meth­yl(phen­yl)amine fragment is disordered over two conformations [occupancy ratio 0.60 (4):0.40 (4)] in the other ligand. In the crystal structure, intra­molecular N—H⋯O hydrogen bonds between the amine and nitrate groups are observed.
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spelling pubmed-29836062010-12-30 Bis(N-{bis­[meth­yl(phen­yl)amino]phos­phor­yl}-2,2,2-trichloro­acetamide)di­nitrato­dioxidouranium(VI) Znovjyak, Kateryna O. Ovchynnikov, Vladimir A. Sliva, Tetyana Yu. Shishkina, Svitlana V. Amirkhanov, Vladimir M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [UO(2) L (2)(NO(3))(2)] {L = N-{bis­[meth­yl(phen­yl)amino]phosphor­yl}-2,2,2-trichloro­acetamide, C(16)H(17)Cl(3)N(3)O(2)P}, the U(VI) ions are eight-coordinated by axial oxido ligands and six equatorial O atoms from the phosphoryl and nitrate groups in a distorted hexa­gonal–bipyramidal geometry. There are disordered fragments in the two coordinating L ligands: the trichloro­methyl group is rotationally disordered between two orientations [occupancy ratio 0.567 (15):0.433 (15)] in one ligand, and a meth­yl(phen­yl)amine fragment is disordered over two conformations [occupancy ratio 0.60 (4):0.40 (4)] in the other ligand. In the crystal structure, intra­molecular N—H⋯O hydrogen bonds between the amine and nitrate groups are observed. International Union of Crystallography 2010-02-17 /pmc/articles/PMC2983606/ /pubmed/21580248 http://dx.doi.org/10.1107/S1600536810005611 Text en © Znovjyak et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Znovjyak, Kateryna O.
Ovchynnikov, Vladimir A.
Sliva, Tetyana Yu.
Shishkina, Svitlana V.
Amirkhanov, Vladimir M.
Bis(N-{bis­[meth­yl(phen­yl)amino]phos­phor­yl}-2,2,2-trichloro­acetamide)di­nitrato­dioxidouranium(VI)
title Bis(N-{bis­[meth­yl(phen­yl)amino]phos­phor­yl}-2,2,2-trichloro­acetamide)di­nitrato­dioxidouranium(VI)
title_full Bis(N-{bis­[meth­yl(phen­yl)amino]phos­phor­yl}-2,2,2-trichloro­acetamide)di­nitrato­dioxidouranium(VI)
title_fullStr Bis(N-{bis­[meth­yl(phen­yl)amino]phos­phor­yl}-2,2,2-trichloro­acetamide)di­nitrato­dioxidouranium(VI)
title_full_unstemmed Bis(N-{bis­[meth­yl(phen­yl)amino]phos­phor­yl}-2,2,2-trichloro­acetamide)di­nitrato­dioxidouranium(VI)
title_short Bis(N-{bis­[meth­yl(phen­yl)amino]phos­phor­yl}-2,2,2-trichloro­acetamide)di­nitrato­dioxidouranium(VI)
title_sort bis(n-{bis­[meth­yl(phen­yl)amino]phos­phor­yl}-2,2,2-trichloro­acetamide)di­nitrato­dioxidouranium(vi)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983606/
https://www.ncbi.nlm.nih.gov/pubmed/21580248
http://dx.doi.org/10.1107/S1600536810005611
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