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{2,2′-[3-Azapentane-1,5-diylbis(nitrilomethylidyne)]dipyrrol-1-yl}(4-methylpyridine)cobalt(III) tetraphenylborate
The title compound, [Co(C(14)H(17)N(5))(C(6)H(7)N)](C(24)H(20)B) or [Co{(pyrrole)(2)dien}(4-Mepy)]BPh(4) where (pyrrole)(2)dien is 2,2′-[(3-azapentane-1,5-diylbis(nitrilomethylidyne)]dipyrrole and 4-Mepy is 4-methylpyridine, contains a pentadentate (pyrrole)(2)dien ligand furnishing an N(5) set...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983608/ https://www.ncbi.nlm.nih.gov/pubmed/21580267 http://dx.doi.org/10.1107/S1600536810006112 |
Sumario: | The title compound, [Co(C(14)H(17)N(5))(C(6)H(7)N)](C(24)H(20)B) or [Co{(pyrrole)(2)dien}(4-Mepy)]BPh(4) where (pyrrole)(2)dien is 2,2′-[(3-azapentane-1,5-diylbis(nitrilomethylidyne)]dipyrrole and 4-Mepy is 4-methylpyridine, contains a pentadentate (pyrrole)(2)dien ligand furnishing an N(5) set, such that two of the pyrrole N atoms and two of the dien N atoms occupy the equatorial positions while one of the imine N atoms of the (pyrrole)(2)dien ligand occupies the axial position. The 4-methylpyridine ligand occupies an axial position trans to one of the imine N atoms of the pentadentate ligand. In the observed conformation of the pentadentate ligand, the pyrrole rings attain asymmetrical positions owing to the structural demands. The geometry of the resulting CoN(6) coordination can be described as distorted octahedral. |
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