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{2,2′-[3-Azapentane-1,5-diylbis(nitrilomethylidyne)]dipyrrol-1-yl}(4-methylpyridine)cobalt(III) tetraphenylborate
The title compound, [Co(C(14)H(17)N(5))(C(6)H(7)N)](C(24)H(20)B) or [Co{(pyrrole)(2)dien}(4-Mepy)]BPh(4) where (pyrrole)(2)dien is 2,2′-[(3-azapentane-1,5-diylbis(nitrilomethylidyne)]dipyrrole and 4-Mepy is 4-methylpyridine, contains a pentadentate (pyrrole)(2)dien ligand furnishing an N(5) set...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983608/ https://www.ncbi.nlm.nih.gov/pubmed/21580267 http://dx.doi.org/10.1107/S1600536810006112 |
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author | Meghdadi, Soraia Amirnasr, Mehdi Mereiter, Kurt Karimi Abdolmaleki, Mahmood |
author_facet | Meghdadi, Soraia Amirnasr, Mehdi Mereiter, Kurt Karimi Abdolmaleki, Mahmood |
author_sort | Meghdadi, Soraia |
collection | PubMed |
description | The title compound, [Co(C(14)H(17)N(5))(C(6)H(7)N)](C(24)H(20)B) or [Co{(pyrrole)(2)dien}(4-Mepy)]BPh(4) where (pyrrole)(2)dien is 2,2′-[(3-azapentane-1,5-diylbis(nitrilomethylidyne)]dipyrrole and 4-Mepy is 4-methylpyridine, contains a pentadentate (pyrrole)(2)dien ligand furnishing an N(5) set, such that two of the pyrrole N atoms and two of the dien N atoms occupy the equatorial positions while one of the imine N atoms of the (pyrrole)(2)dien ligand occupies the axial position. The 4-methylpyridine ligand occupies an axial position trans to one of the imine N atoms of the pentadentate ligand. In the observed conformation of the pentadentate ligand, the pyrrole rings attain asymmetrical positions owing to the structural demands. The geometry of the resulting CoN(6) coordination can be described as distorted octahedral. |
format | Text |
id | pubmed-2983608 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29836082010-12-30 {2,2′-[3-Azapentane-1,5-diylbis(nitrilomethylidyne)]dipyrrol-1-yl}(4-methylpyridine)cobalt(III) tetraphenylborate Meghdadi, Soraia Amirnasr, Mehdi Mereiter, Kurt Karimi Abdolmaleki, Mahmood Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Co(C(14)H(17)N(5))(C(6)H(7)N)](C(24)H(20)B) or [Co{(pyrrole)(2)dien}(4-Mepy)]BPh(4) where (pyrrole)(2)dien is 2,2′-[(3-azapentane-1,5-diylbis(nitrilomethylidyne)]dipyrrole and 4-Mepy is 4-methylpyridine, contains a pentadentate (pyrrole)(2)dien ligand furnishing an N(5) set, such that two of the pyrrole N atoms and two of the dien N atoms occupy the equatorial positions while one of the imine N atoms of the (pyrrole)(2)dien ligand occupies the axial position. The 4-methylpyridine ligand occupies an axial position trans to one of the imine N atoms of the pentadentate ligand. In the observed conformation of the pentadentate ligand, the pyrrole rings attain asymmetrical positions owing to the structural demands. The geometry of the resulting CoN(6) coordination can be described as distorted octahedral. International Union of Crystallography 2010-02-24 /pmc/articles/PMC2983608/ /pubmed/21580267 http://dx.doi.org/10.1107/S1600536810006112 Text en © Meghdadi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Meghdadi, Soraia Amirnasr, Mehdi Mereiter, Kurt Karimi Abdolmaleki, Mahmood {2,2′-[3-Azapentane-1,5-diylbis(nitrilomethylidyne)]dipyrrol-1-yl}(4-methylpyridine)cobalt(III) tetraphenylborate |
title | {2,2′-[3-Azapentane-1,5-diylbis(nitrilomethylidyne)]dipyrrol-1-yl}(4-methylpyridine)cobalt(III) tetraphenylborate |
title_full | {2,2′-[3-Azapentane-1,5-diylbis(nitrilomethylidyne)]dipyrrol-1-yl}(4-methylpyridine)cobalt(III) tetraphenylborate |
title_fullStr | {2,2′-[3-Azapentane-1,5-diylbis(nitrilomethylidyne)]dipyrrol-1-yl}(4-methylpyridine)cobalt(III) tetraphenylborate |
title_full_unstemmed | {2,2′-[3-Azapentane-1,5-diylbis(nitrilomethylidyne)]dipyrrol-1-yl}(4-methylpyridine)cobalt(III) tetraphenylborate |
title_short | {2,2′-[3-Azapentane-1,5-diylbis(nitrilomethylidyne)]dipyrrol-1-yl}(4-methylpyridine)cobalt(III) tetraphenylborate |
title_sort | {2,2′-[3-azapentane-1,5-diylbis(nitrilomethylidyne)]dipyrrol-1-yl}(4-methylpyridine)cobalt(iii) tetraphenylborate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983608/ https://www.ncbi.nlm.nih.gov/pubmed/21580267 http://dx.doi.org/10.1107/S1600536810006112 |
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