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{2,2′-[3-Aza­pentane-1,5-diylbis(nitrilo­methyl­idyne)]dipyrrol-1-yl}(4-methyl­pyridine)cobalt(III) tetra­phenyl­borate

The title compound, [Co(C(14)H(17)N(5))(C(6)H(7)N)](C(24)H(20)B) or [Co{(pyrrole)(2)dien}(4-Mepy)]BPh(4) where (pyrrole)(2)dien is 2,2′-[(3-aza­pentane-1,5-diylbis(nitrilo­methyl­idyne)]dipyrrole and 4-Mepy is 4-methyl­pyridine, contains a penta­dentate (pyrrole)(2)dien ligand furnishing an N(5) set...

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Detalles Bibliográficos
Autores principales: Meghdadi, Soraia, Amirnasr, Mehdi, Mereiter, Kurt, Karimi Abdolmaleki, Mahmood
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983608/
https://www.ncbi.nlm.nih.gov/pubmed/21580267
http://dx.doi.org/10.1107/S1600536810006112
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author Meghdadi, Soraia
Amirnasr, Mehdi
Mereiter, Kurt
Karimi Abdolmaleki, Mahmood
author_facet Meghdadi, Soraia
Amirnasr, Mehdi
Mereiter, Kurt
Karimi Abdolmaleki, Mahmood
author_sort Meghdadi, Soraia
collection PubMed
description The title compound, [Co(C(14)H(17)N(5))(C(6)H(7)N)](C(24)H(20)B) or [Co{(pyrrole)(2)dien}(4-Mepy)]BPh(4) where (pyrrole)(2)dien is 2,2′-[(3-aza­pentane-1,5-diylbis(nitrilo­methyl­idyne)]dipyrrole and 4-Mepy is 4-methyl­pyridine, contains a penta­dentate (pyrrole)(2)dien ligand furnishing an N(5) set, such that two of the pyrrole N atoms and two of the dien N atoms occupy the equatorial positions while one of the imine N atoms of the (pyrrole)(2)dien ligand occupies the axial position. The 4-methyl­pyridine ligand occupies an axial position trans to one of the imine N atoms of the penta­dentate ligand. In the observed conformation of the penta­dentate ligand, the pyrrole rings attain asymmetrical positions owing to the structural demands. The geometry of the resulting CoN(6) coordination can be described as distorted octa­hedral.
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spelling pubmed-29836082010-12-30 {2,2′-[3-Aza­pentane-1,5-diylbis(nitrilo­methyl­idyne)]dipyrrol-1-yl}(4-methyl­pyridine)cobalt(III) tetra­phenyl­borate Meghdadi, Soraia Amirnasr, Mehdi Mereiter, Kurt Karimi Abdolmaleki, Mahmood Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Co(C(14)H(17)N(5))(C(6)H(7)N)](C(24)H(20)B) or [Co{(pyrrole)(2)dien}(4-Mepy)]BPh(4) where (pyrrole)(2)dien is 2,2′-[(3-aza­pentane-1,5-diylbis(nitrilo­methyl­idyne)]dipyrrole and 4-Mepy is 4-methyl­pyridine, contains a penta­dentate (pyrrole)(2)dien ligand furnishing an N(5) set, such that two of the pyrrole N atoms and two of the dien N atoms occupy the equatorial positions while one of the imine N atoms of the (pyrrole)(2)dien ligand occupies the axial position. The 4-methyl­pyridine ligand occupies an axial position trans to one of the imine N atoms of the penta­dentate ligand. In the observed conformation of the penta­dentate ligand, the pyrrole rings attain asymmetrical positions owing to the structural demands. The geometry of the resulting CoN(6) coordination can be described as distorted octa­hedral. International Union of Crystallography 2010-02-24 /pmc/articles/PMC2983608/ /pubmed/21580267 http://dx.doi.org/10.1107/S1600536810006112 Text en © Meghdadi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Meghdadi, Soraia
Amirnasr, Mehdi
Mereiter, Kurt
Karimi Abdolmaleki, Mahmood
{2,2′-[3-Aza­pentane-1,5-diylbis(nitrilo­methyl­idyne)]dipyrrol-1-yl}(4-methyl­pyridine)cobalt(III) tetra­phenyl­borate
title {2,2′-[3-Aza­pentane-1,5-diylbis(nitrilo­methyl­idyne)]dipyrrol-1-yl}(4-methyl­pyridine)cobalt(III) tetra­phenyl­borate
title_full {2,2′-[3-Aza­pentane-1,5-diylbis(nitrilo­methyl­idyne)]dipyrrol-1-yl}(4-methyl­pyridine)cobalt(III) tetra­phenyl­borate
title_fullStr {2,2′-[3-Aza­pentane-1,5-diylbis(nitrilo­methyl­idyne)]dipyrrol-1-yl}(4-methyl­pyridine)cobalt(III) tetra­phenyl­borate
title_full_unstemmed {2,2′-[3-Aza­pentane-1,5-diylbis(nitrilo­methyl­idyne)]dipyrrol-1-yl}(4-methyl­pyridine)cobalt(III) tetra­phenyl­borate
title_short {2,2′-[3-Aza­pentane-1,5-diylbis(nitrilo­methyl­idyne)]dipyrrol-1-yl}(4-methyl­pyridine)cobalt(III) tetra­phenyl­borate
title_sort {2,2′-[3-aza­pentane-1,5-diylbis(nitrilo­methyl­idyne)]dipyrrol-1-yl}(4-methyl­pyridine)cobalt(iii) tetra­phenyl­borate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983608/
https://www.ncbi.nlm.nih.gov/pubmed/21580267
http://dx.doi.org/10.1107/S1600536810006112
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