Dibenzyl 3,3′-diethyl-4,4′-dimethyl-2,2′-methylenebis(pyrrole-5-carboxylate)

In the title compound, C(31)H(34)N(2)O(4), the two pyrrole rings are bent around the central methyl­ene C atom, making a dihedral angle of 64.83 (7)°. In the crystal, mol­ecules are linked into dimers via N—H⋯O=C hydrogen bonds. These dimers are packed through π⋯π inter­actions between neighboring p...

Descripción completa

Detalles Bibliográficos
Autor principal: Kim, Hee-Joon
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983617/
https://www.ncbi.nlm.nih.gov/pubmed/21580334
http://dx.doi.org/10.1107/S1600536810004459
_version_ 1782191916027215872
author Kim, Hee-Joon
author_facet Kim, Hee-Joon
author_sort Kim, Hee-Joon
collection PubMed
description In the title compound, C(31)H(34)N(2)O(4), the two pyrrole rings are bent around the central methyl­ene C atom, making a dihedral angle of 64.83 (7)°. In the crystal, mol­ecules are linked into dimers via N—H⋯O=C hydrogen bonds. These dimers are packed through π⋯π inter­actions between neighboring pyrrole rings with a separation between the mean planes of symmetry-related pyrrole rings of 3.61 (2) Å and a centroid–centroid distance of 4.33 Å. Parallel phenyl groups in neighboring dimers also exhibit efficient π⋯π inter­actions, characterized by an inter­plane separation of 3.378 (8) Å and a centroid–centroid distance of 3.97 Å.
format Text
id pubmed-2983617
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29836172010-12-30 Dibenzyl 3,3′-diethyl-4,4′-dimethyl-2,2′-methylenebis(pyrrole-5-carboxylate) Kim, Hee-Joon Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(31)H(34)N(2)O(4), the two pyrrole rings are bent around the central methyl­ene C atom, making a dihedral angle of 64.83 (7)°. In the crystal, mol­ecules are linked into dimers via N—H⋯O=C hydrogen bonds. These dimers are packed through π⋯π inter­actions between neighboring pyrrole rings with a separation between the mean planes of symmetry-related pyrrole rings of 3.61 (2) Å and a centroid–centroid distance of 4.33 Å. Parallel phenyl groups in neighboring dimers also exhibit efficient π⋯π inter­actions, characterized by an inter­plane separation of 3.378 (8) Å and a centroid–centroid distance of 3.97 Å. International Union of Crystallography 2010-02-10 /pmc/articles/PMC2983617/ /pubmed/21580334 http://dx.doi.org/10.1107/S1600536810004459 Text en © Hee-Joon Kim 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kim, Hee-Joon
Dibenzyl 3,3′-diethyl-4,4′-dimethyl-2,2′-methylenebis(pyrrole-5-carboxylate)
title Dibenzyl 3,3′-diethyl-4,4′-dimethyl-2,2′-methylenebis(pyrrole-5-carboxylate)
title_full Dibenzyl 3,3′-diethyl-4,4′-dimethyl-2,2′-methylenebis(pyrrole-5-carboxylate)
title_fullStr Dibenzyl 3,3′-diethyl-4,4′-dimethyl-2,2′-methylenebis(pyrrole-5-carboxylate)
title_full_unstemmed Dibenzyl 3,3′-diethyl-4,4′-dimethyl-2,2′-methylenebis(pyrrole-5-carboxylate)
title_short Dibenzyl 3,3′-diethyl-4,4′-dimethyl-2,2′-methylenebis(pyrrole-5-carboxylate)
title_sort dibenzyl 3,3′-diethyl-4,4′-dimethyl-2,2′-methylenebis(pyrrole-5-carboxylate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983617/
https://www.ncbi.nlm.nih.gov/pubmed/21580334
http://dx.doi.org/10.1107/S1600536810004459
work_keys_str_mv AT kimheejoon dibenzyl33diethyl44dimethyl22methylenebispyrrole5carboxylate

Ejemplares similares