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cis-Dichloridobis(dimethoxy­phenyl­phosphine)palladium(II)

The title compound, [PdCl(2)(C(8)H(11)O(2)P)(2)], has a comparable structure to those of related palladium dichloride complexes containing trimethyl phosphinite and methyl diphenyl phosphinite. The Pd atom is located on a crystallographic twofold rotation axis: thus, there is just one half-mol­ecule...

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Detalles Bibliográficos
Autores principales: Slawin, Alexandra M. Z., Waddell, Paul G., Woollins, J. Derek
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983618/
https://www.ncbi.nlm.nih.gov/pubmed/21580259
http://dx.doi.org/10.1107/S1600536810006471
Descripción
Sumario:The title compound, [PdCl(2)(C(8)H(11)O(2)P)(2)], has a comparable structure to those of related palladium dichloride complexes containing trimethyl phosphinite and methyl diphenyl phosphinite. The Pd atom is located on a crystallographic twofold rotation axis: thus, there is just one half-mol­ecule in the asymmetric unit. The structure is isomorphous with the platinum analogue cis-[PtCl(2){P(OMe)(2)Ph}(2)].