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2-Amino-5-bromo­pyridinium 3-amino­benzoate

In the title salt, C(5)H(6)BrN(2) (+)·C(7)H(6)NO(2) (−), the pyridine N atom of the 2-amino-5-bromo­pyridine mol­ecule is protonated. In the crystal, the protonated N atom and the 2-amino group are hydrogen-bonded to the carboxyl­ate O atoms via a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8...

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Detalles Bibliográficos
Autores principales: Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983620/
https://www.ncbi.nlm.nih.gov/pubmed/21580412
http://dx.doi.org/10.1107/S1600536810006288
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author Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Hemamalini, Madhukar
collection PubMed
description In the title salt, C(5)H(6)BrN(2) (+)·C(7)H(6)NO(2) (−), the pyridine N atom of the 2-amino-5-bromo­pyridine mol­ecule is protonated. In the crystal, the protonated N atom and the 2-amino group are hydrogen-bonded to the carboxyl­ate O atoms via a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. Two inversion-related 3-amino­benzoate anions are linked through N—H⋯O hydrogen-bonds, forming an R (2) (2)(14) ring motif. The crystal structure is further stabilized by π⋯π inter­actions involving the benzene and pyridinium rings with a centroid–centroid distance of 3.7743 (15) Å.
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spelling pubmed-29836202010-12-30 2-Amino-5-bromo­pyridinium 3-amino­benzoate Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(5)H(6)BrN(2) (+)·C(7)H(6)NO(2) (−), the pyridine N atom of the 2-amino-5-bromo­pyridine mol­ecule is protonated. In the crystal, the protonated N atom and the 2-amino group are hydrogen-bonded to the carboxyl­ate O atoms via a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. Two inversion-related 3-amino­benzoate anions are linked through N—H⋯O hydrogen-bonds, forming an R (2) (2)(14) ring motif. The crystal structure is further stabilized by π⋯π inter­actions involving the benzene and pyridinium rings with a centroid–centroid distance of 3.7743 (15) Å. International Union of Crystallography 2010-02-20 /pmc/articles/PMC2983620/ /pubmed/21580412 http://dx.doi.org/10.1107/S1600536810006288 Text en © Hemamalini and Fun 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hemamalini, Madhukar
Fun, Hoong-Kun
2-Amino-5-bromo­pyridinium 3-amino­benzoate
title 2-Amino-5-bromo­pyridinium 3-amino­benzoate
title_full 2-Amino-5-bromo­pyridinium 3-amino­benzoate
title_fullStr 2-Amino-5-bromo­pyridinium 3-amino­benzoate
title_full_unstemmed 2-Amino-5-bromo­pyridinium 3-amino­benzoate
title_short 2-Amino-5-bromo­pyridinium 3-amino­benzoate
title_sort 2-amino-5-bromo­pyridinium 3-amino­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983620/
https://www.ncbi.nlm.nih.gov/pubmed/21580412
http://dx.doi.org/10.1107/S1600536810006288
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