Bis(tetra­phenyl­phospho­nium) tetra­iodidomanganate(II) acetone monosolvate

The title compound, (C(24)H(20)P)(2)[MnI(4)]·(CH(3))(2)CO, prepared from the reaction of manganese powder, iodine and tetra­phenyl­phospho­nium iodide in acetone shows a tetra­hedral complex anion [Mn—I = 2.6868 (5)–2.7281 (4) Å and I—Mn—I = 104.011 (13)–116.164 (15)°], two tetra­phenyl­phospho­nium...

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Detalles Bibliográficos
Autores principales: Jalilian, Ehsan, Lidin, Sven
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983621/
https://www.ncbi.nlm.nih.gov/pubmed/21580270
http://dx.doi.org/10.1107/S1600536810006732
Descripción
Sumario:The title compound, (C(24)H(20)P)(2)[MnI(4)]·(CH(3))(2)CO, prepared from the reaction of manganese powder, iodine and tetra­phenyl­phospho­nium iodide in acetone shows a tetra­hedral complex anion [Mn—I = 2.6868 (5)–2.7281 (4) Å and I—Mn—I = 104.011 (13)–116.164 (15)°], two tetra­phenyl­phospho­nium cations and one mol­ecule of acetone.

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