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Bis[ethyl(2-hydroxyethyl)azanium] 2,2′-disulfanediyldibenzoate
The asymmetric unit of the title salt, 2C(4)H(12)NO(+)·C(14)H(8)O(4)S(2) (2−), contains an ethyl(2-hydroxy)aminium cation and half a 2,2′-disulfanediyldibenzoate anion, with the latter disposed about a twofold axis. The cation is a straight chain with the exception of the terminal hydroxy group [...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983623/ https://www.ncbi.nlm.nih.gov/pubmed/21580443 http://dx.doi.org/10.1107/S1600536810006781 |
Sumario: | The asymmetric unit of the title salt, 2C(4)H(12)NO(+)·C(14)H(8)O(4)S(2) (2−), contains an ethyl(2-hydroxy)aminium cation and half a 2,2′-disulfanediyldibenzoate anion, with the latter disposed about a twofold axis. The cation is a straight chain with the exception of the terminal hydroxy group [the N—C—C—O torsion angle is 66.5 (2)°]. A twisted conformation is found for the anion [the C—S—S—C torsion angle is 91.51 (9)° and the dihedral angle between the rings is 81.01 (4)°]. A supramolecular chain with base vector [101] and a tubular topology is formed in the crystal structure mediated by charge-assisted O—H⋯O(−) and N(+)—H⋯O(−) hydrogen bonding. |
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