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Bis[eth­yl(2-hydroxy­ethyl)aza­nium] 2,2′-disulfanediyldibenzoate

The asymmetric unit of the title salt, 2C(4)H(12)NO(+)·C(14)H(8)O(4)S(2) (2−), contains an eth­yl(2-hydr­oxy)aminium cation and half a 2,2′-disulfanediyldibenzoate anion, with the latter disposed about a twofold axis. The cation is a straight chain with the exception of the terminal hydr­oxy group [...

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Detalles Bibliográficos
Autores principales: Broker, Grant A., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983623/
https://www.ncbi.nlm.nih.gov/pubmed/21580443
http://dx.doi.org/10.1107/S1600536810006781
Descripción
Sumario:The asymmetric unit of the title salt, 2C(4)H(12)NO(+)·C(14)H(8)O(4)S(2) (2−), contains an eth­yl(2-hydr­oxy)aminium cation and half a 2,2′-disulfanediyldibenzoate anion, with the latter disposed about a twofold axis. The cation is a straight chain with the exception of the terminal hydr­oxy group [the N—C—C—O torsion angle is 66.5 (2)°]. A twisted conformation is found for the anion [the C—S—S—C torsion angle is 91.51 (9)° and the dihedral angle between the rings is 81.01 (4)°]. A supra­molecular chain with base vector [101] and a tubular topology is formed in the crystal structure mediated by charge-assisted O—H⋯O(−) and N(+)—H⋯O(−) hydrogen bonding.