Bis[eth­yl(2-hydroxy­ethyl)aza­nium] 2,2′-disulfanediyldibenzoate

The asymmetric unit of the title salt, 2C(4)H(12)NO(+)·C(14)H(8)O(4)S(2) (2−), contains an eth­yl(2-hydr­oxy)aminium cation and half a 2,2′-disulfanediyldibenzoate anion, with the latter disposed about a twofold axis. The cation is a straight chain with the exception of the terminal hydr­oxy group [...

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Detalles Bibliográficos
Autores principales: Broker, Grant A., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983623/
https://www.ncbi.nlm.nih.gov/pubmed/21580443
http://dx.doi.org/10.1107/S1600536810006781
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author Broker, Grant A.
Tiekink, Edward R. T.
author_facet Broker, Grant A.
Tiekink, Edward R. T.
author_sort Broker, Grant A.
collection PubMed
description The asymmetric unit of the title salt, 2C(4)H(12)NO(+)·C(14)H(8)O(4)S(2) (2−), contains an eth­yl(2-hydr­oxy)aminium cation and half a 2,2′-disulfanediyldibenzoate anion, with the latter disposed about a twofold axis. The cation is a straight chain with the exception of the terminal hydr­oxy group [the N—C—C—O torsion angle is 66.5 (2)°]. A twisted conformation is found for the anion [the C—S—S—C torsion angle is 91.51 (9)° and the dihedral angle between the rings is 81.01 (4)°]. A supra­molecular chain with base vector [101] and a tubular topology is formed in the crystal structure mediated by charge-assisted O—H⋯O(−) and N(+)—H⋯O(−) hydrogen bonding.
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spelling pubmed-29836232010-12-30 Bis[eth­yl(2-hydroxy­ethyl)aza­nium] 2,2′-disulfanediyldibenzoate Broker, Grant A. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title salt, 2C(4)H(12)NO(+)·C(14)H(8)O(4)S(2) (2−), contains an eth­yl(2-hydr­oxy)aminium cation and half a 2,2′-disulfanediyldibenzoate anion, with the latter disposed about a twofold axis. The cation is a straight chain with the exception of the terminal hydr­oxy group [the N—C—C—O torsion angle is 66.5 (2)°]. A twisted conformation is found for the anion [the C—S—S—C torsion angle is 91.51 (9)° and the dihedral angle between the rings is 81.01 (4)°]. A supra­molecular chain with base vector [101] and a tubular topology is formed in the crystal structure mediated by charge-assisted O—H⋯O(−) and N(+)—H⋯O(−) hydrogen bonding. International Union of Crystallography 2010-02-27 /pmc/articles/PMC2983623/ /pubmed/21580443 http://dx.doi.org/10.1107/S1600536810006781 Text en © Broker and Tiekink 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Broker, Grant A.
Tiekink, Edward R. T.
Bis[eth­yl(2-hydroxy­ethyl)aza­nium] 2,2′-disulfanediyldibenzoate
title Bis[eth­yl(2-hydroxy­ethyl)aza­nium] 2,2′-disulfanediyldibenzoate
title_full Bis[eth­yl(2-hydroxy­ethyl)aza­nium] 2,2′-disulfanediyldibenzoate
title_fullStr Bis[eth­yl(2-hydroxy­ethyl)aza­nium] 2,2′-disulfanediyldibenzoate
title_full_unstemmed Bis[eth­yl(2-hydroxy­ethyl)aza­nium] 2,2′-disulfanediyldibenzoate
title_short Bis[eth­yl(2-hydroxy­ethyl)aza­nium] 2,2′-disulfanediyldibenzoate
title_sort bis[eth­yl(2-hydroxy­ethyl)aza­nium] 2,2′-disulfanediyldibenzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983623/
https://www.ncbi.nlm.nih.gov/pubmed/21580443
http://dx.doi.org/10.1107/S1600536810006781
work_keys_str_mv AT brokergranta bisethyl2hydroxyethylazanium22disulfanediyldibenzoate
AT tiekinkedwardrt bisethyl2hydroxyethylazanium22disulfanediyldibenzoate

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