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(5-Ammonio­pent­yl)triphenyl­phospho­nium dibromide ethanol solvate

The alkyl­ammonium chain of the dication in the title mitochondrially targeted (5-ammonio­pent­yl)triphenyl­­phos­pho­nium dibromide ethanol solvate, C(23)H(28)NP(2+)·2Br(−)·C(2)H(6)O, is almost planar (r.m.s deviation = 0.0716 Å for all non-H atoms) and in the extended form, maximizing the P⋯N dist...

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Detalles Bibliográficos
Autor principal: Evans, Cameron
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983624/
https://www.ncbi.nlm.nih.gov/pubmed/21580280
http://dx.doi.org/10.1107/S1600536810003193
Descripción
Sumario:The alkyl­ammonium chain of the dication in the title mitochondrially targeted (5-ammonio­pent­yl)triphenyl­­phos­pho­nium dibromide ethanol solvate, C(23)H(28)NP(2+)·2Br(−)·C(2)H(6)O, is almost planar (r.m.s deviation = 0.0716 Å for all non-H atoms) and in the extended form, maximizing the P⋯N distance [7.716 (2) Å]. The ions and solvent are linked within the crystal by N—H⋯Br, N—H⋯O and O—H⋯Br hydrogen-bonding inter­actions, forming C (3) (2)(6) chains along the b axis, with secondary C—H⋯Br and C—H⋯O inter­actions cross-linking the chains.