μ-Succinato-bis­[aqua­(2,2′:6′,2′′-terpyridine)copper(II)] dinitrate dihydrate

The title compound, [Cu(2)(C(4)H(4)O(4))(C(15)H(11)N(3))(2)(H(2)O)(2)](NO(3))(2)·2H(2)O, was synthesized under hydro­thermal conditions. The dinuclear copper complex is located on a crystallographic inversion centre. The Cu(II) ion is penta­coordinated in a tetra­gonal–pyramidal geometry, with one O...

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Detalles Bibliográficos
Autores principales: Mei, Chongzhen, Lei, Qingduo, Zhang, Peng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983631/
https://www.ncbi.nlm.nih.gov/pubmed/21580277
http://dx.doi.org/10.1107/S1600536810006811
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author Mei, Chongzhen
Lei, Qingduo
Zhang, Peng
author_facet Mei, Chongzhen
Lei, Qingduo
Zhang, Peng
author_sort Mei, Chongzhen
collection PubMed
description The title compound, [Cu(2)(C(4)H(4)O(4))(C(15)H(11)N(3))(2)(H(2)O)(2)](NO(3))(2)·2H(2)O, was synthesized under hydro­thermal conditions. The dinuclear copper complex is located on a crystallographic inversion centre. The Cu(II) ion is penta­coordinated in a tetra­gonal–pyramidal geometry, with one O atom of a succinate dianion and three N atoms of a 2,2′:6′,2′′-terpyridine ligand occupying the basal plane, and a water O atom located at the apical site. In the crystal structure, O—H⋯O hydrogen bonding links the mol­ecules into a chain parallel to the a axis.
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spelling pubmed-29836312010-12-30 μ-Succinato-bis­[aqua­(2,2′:6′,2′′-terpyridine)copper(II)] dinitrate dihydrate Mei, Chongzhen Lei, Qingduo Zhang, Peng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(2)(C(4)H(4)O(4))(C(15)H(11)N(3))(2)(H(2)O)(2)](NO(3))(2)·2H(2)O, was synthesized under hydro­thermal conditions. The dinuclear copper complex is located on a crystallographic inversion centre. The Cu(II) ion is penta­coordinated in a tetra­gonal–pyramidal geometry, with one O atom of a succinate dianion and three N atoms of a 2,2′:6′,2′′-terpyridine ligand occupying the basal plane, and a water O atom located at the apical site. In the crystal structure, O—H⋯O hydrogen bonding links the mol­ecules into a chain parallel to the a axis. International Union of Crystallography 2010-02-27 /pmc/articles/PMC2983631/ /pubmed/21580277 http://dx.doi.org/10.1107/S1600536810006811 Text en © Mei et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mei, Chongzhen
Lei, Qingduo
Zhang, Peng
μ-Succinato-bis­[aqua­(2,2′:6′,2′′-terpyridine)copper(II)] dinitrate dihydrate
title μ-Succinato-bis­[aqua­(2,2′:6′,2′′-terpyridine)copper(II)] dinitrate dihydrate
title_full μ-Succinato-bis­[aqua­(2,2′:6′,2′′-terpyridine)copper(II)] dinitrate dihydrate
title_fullStr μ-Succinato-bis­[aqua­(2,2′:6′,2′′-terpyridine)copper(II)] dinitrate dihydrate
title_full_unstemmed μ-Succinato-bis­[aqua­(2,2′:6′,2′′-terpyridine)copper(II)] dinitrate dihydrate
title_short μ-Succinato-bis­[aqua­(2,2′:6′,2′′-terpyridine)copper(II)] dinitrate dihydrate
title_sort μ-succinato-bis­[aqua­(2,2′:6′,2′′-terpyridine)copper(ii)] dinitrate dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983631/
https://www.ncbi.nlm.nih.gov/pubmed/21580277
http://dx.doi.org/10.1107/S1600536810006811
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AT zhangpeng msuccinatobisaqua2262terpyridinecopperiidinitratedihydrate

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