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Dichloridobis(4-methyl­benz­yl)(1,10-phenanthroline-κ(2) N,N′)tin(IV)

The tin(IV) atom in the title compound, [Sn(C(8)H(9))(2)Cl(2)(C(12)H(8)N(2))], is chelated by the N-heterocycle and bonded to two C atoms and two chloride ions in an SnC(2)Cl(2)N(2) octa­hedral coordination environment with the C atoms trans to each other. The dihedral angles between the heterocycle...

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Detalles Bibliográficos
Autores principales: Keng, Thy Chun, Lo, Kong Mun, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983632/
https://www.ncbi.nlm.nih.gov/pubmed/21580246
http://dx.doi.org/10.1107/S1600536810005672
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author Keng, Thy Chun
Lo, Kong Mun
Ng, Seik Weng
author_facet Keng, Thy Chun
Lo, Kong Mun
Ng, Seik Weng
author_sort Keng, Thy Chun
collection PubMed
description The tin(IV) atom in the title compound, [Sn(C(8)H(9))(2)Cl(2)(C(12)H(8)N(2))], is chelated by the N-heterocycle and bonded to two C atoms and two chloride ions in an SnC(2)Cl(2)N(2) octa­hedral coordination environment with the C atoms trans to each other. The dihedral angles between the heterocycle ring system and the benzene rings of the 4-methyl­benzyl groups are 21.20 (12) and 28.71 (11)°.
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spelling pubmed-29836322010-12-30 Dichloridobis(4-methyl­benz­yl)(1,10-phenanthroline-κ(2) N,N′)tin(IV) Keng, Thy Chun Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The tin(IV) atom in the title compound, [Sn(C(8)H(9))(2)Cl(2)(C(12)H(8)N(2))], is chelated by the N-heterocycle and bonded to two C atoms and two chloride ions in an SnC(2)Cl(2)N(2) octa­hedral coordination environment with the C atoms trans to each other. The dihedral angles between the heterocycle ring system and the benzene rings of the 4-methyl­benzyl groups are 21.20 (12) and 28.71 (11)°. International Union of Crystallography 2010-02-17 /pmc/articles/PMC2983632/ /pubmed/21580246 http://dx.doi.org/10.1107/S1600536810005672 Text en © Keng et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Keng, Thy Chun
Lo, Kong Mun
Ng, Seik Weng
Dichloridobis(4-methyl­benz­yl)(1,10-phenanthroline-κ(2) N,N′)tin(IV)
title Dichloridobis(4-methyl­benz­yl)(1,10-phenanthroline-κ(2) N,N′)tin(IV)
title_full Dichloridobis(4-methyl­benz­yl)(1,10-phenanthroline-κ(2) N,N′)tin(IV)
title_fullStr Dichloridobis(4-methyl­benz­yl)(1,10-phenanthroline-κ(2) N,N′)tin(IV)
title_full_unstemmed Dichloridobis(4-methyl­benz­yl)(1,10-phenanthroline-κ(2) N,N′)tin(IV)
title_short Dichloridobis(4-methyl­benz­yl)(1,10-phenanthroline-κ(2) N,N′)tin(IV)
title_sort dichloridobis(4-methyl­benz­yl)(1,10-phenanthroline-κ(2) n,n′)tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983632/
https://www.ncbi.nlm.nih.gov/pubmed/21580246
http://dx.doi.org/10.1107/S1600536810005672
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