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Dichloridobis(4-methylbenzyl)(1,10-phenanthroline-κ(2) N,N′)tin(IV)
The tin(IV) atom in the title compound, [Sn(C(8)H(9))(2)Cl(2)(C(12)H(8)N(2))], is chelated by the N-heterocycle and bonded to two C atoms and two chloride ions in an SnC(2)Cl(2)N(2) octahedral coordination environment with the C atoms trans to each other. The dihedral angles between the heterocycle...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983632/ https://www.ncbi.nlm.nih.gov/pubmed/21580246 http://dx.doi.org/10.1107/S1600536810005672 |
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author | Keng, Thy Chun Lo, Kong Mun Ng, Seik Weng |
author_facet | Keng, Thy Chun Lo, Kong Mun Ng, Seik Weng |
author_sort | Keng, Thy Chun |
collection | PubMed |
description | The tin(IV) atom in the title compound, [Sn(C(8)H(9))(2)Cl(2)(C(12)H(8)N(2))], is chelated by the N-heterocycle and bonded to two C atoms and two chloride ions in an SnC(2)Cl(2)N(2) octahedral coordination environment with the C atoms trans to each other. The dihedral angles between the heterocycle ring system and the benzene rings of the 4-methylbenzyl groups are 21.20 (12) and 28.71 (11)°. |
format | Text |
id | pubmed-2983632 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29836322010-12-30 Dichloridobis(4-methylbenzyl)(1,10-phenanthroline-κ(2) N,N′)tin(IV) Keng, Thy Chun Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The tin(IV) atom in the title compound, [Sn(C(8)H(9))(2)Cl(2)(C(12)H(8)N(2))], is chelated by the N-heterocycle and bonded to two C atoms and two chloride ions in an SnC(2)Cl(2)N(2) octahedral coordination environment with the C atoms trans to each other. The dihedral angles between the heterocycle ring system and the benzene rings of the 4-methylbenzyl groups are 21.20 (12) and 28.71 (11)°. International Union of Crystallography 2010-02-17 /pmc/articles/PMC2983632/ /pubmed/21580246 http://dx.doi.org/10.1107/S1600536810005672 Text en © Keng et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Keng, Thy Chun Lo, Kong Mun Ng, Seik Weng Dichloridobis(4-methylbenzyl)(1,10-phenanthroline-κ(2) N,N′)tin(IV) |
title | Dichloridobis(4-methylbenzyl)(1,10-phenanthroline-κ(2)
N,N′)tin(IV) |
title_full | Dichloridobis(4-methylbenzyl)(1,10-phenanthroline-κ(2)
N,N′)tin(IV) |
title_fullStr | Dichloridobis(4-methylbenzyl)(1,10-phenanthroline-κ(2)
N,N′)tin(IV) |
title_full_unstemmed | Dichloridobis(4-methylbenzyl)(1,10-phenanthroline-κ(2)
N,N′)tin(IV) |
title_short | Dichloridobis(4-methylbenzyl)(1,10-phenanthroline-κ(2)
N,N′)tin(IV) |
title_sort | dichloridobis(4-methylbenzyl)(1,10-phenanthroline-κ(2)
n,n′)tin(iv) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983632/ https://www.ncbi.nlm.nih.gov/pubmed/21580246 http://dx.doi.org/10.1107/S1600536810005672 |
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