2-Amino-4,6-dimethyl­pyrimidine–anthranilic acid (1/1)

In the title 1:1 adduct, C(6)H(9)N(3)·C(7)H(7)NO(2), the crystal structure is stabilized by hydrogen bonds involving two different R (2) (2)(8) motifs. One of them is formed by the inter­action of 2-amino-4,6-dimethyl­pyrimidine (AMPY) with the carboxyl group of anthranilic acid (AA) through N—H⋯O a...

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Detalles Bibliográficos
Autores principales: Ebenezer, Samuel, Muthiah, Packianathan Thomas
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983637/
https://www.ncbi.nlm.nih.gov/pubmed/21580290
http://dx.doi.org/10.1107/S1600536810003661
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author Ebenezer, Samuel
Muthiah, Packianathan Thomas
author_facet Ebenezer, Samuel
Muthiah, Packianathan Thomas
author_sort Ebenezer, Samuel
collection PubMed
description In the title 1:1 adduct, C(6)H(9)N(3)·C(7)H(7)NO(2), the crystal structure is stabilized by hydrogen bonds involving two different R (2) (2)(8) motifs. One of them is formed by the inter­action of 2-amino-4,6-dimethyl­pyrimidine (AMPY) with the carboxyl group of anthranilic acid (AA) through N—H⋯O and O—H⋯N hydrogen bonds, whereas the other is formed through the inter­action of two centrosymmetrically related pyrimidines involving N—H⋯N hydrogen bonds. These two combined motifs form a heterotetra­mer. The heterotetra­mer sheets are stacked into three-dimensional network.
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spelling pubmed-29836372010-12-30 2-Amino-4,6-dimethyl­pyrimidine–anthranilic acid (1/1) Ebenezer, Samuel Muthiah, Packianathan Thomas Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title 1:1 adduct, C(6)H(9)N(3)·C(7)H(7)NO(2), the crystal structure is stabilized by hydrogen bonds involving two different R (2) (2)(8) motifs. One of them is formed by the inter­action of 2-amino-4,6-dimethyl­pyrimidine (AMPY) with the carboxyl group of anthranilic acid (AA) through N—H⋯O and O—H⋯N hydrogen bonds, whereas the other is formed through the inter­action of two centrosymmetrically related pyrimidines involving N—H⋯N hydrogen bonds. These two combined motifs form a heterotetra­mer. The heterotetra­mer sheets are stacked into three-dimensional network. International Union of Crystallography 2010-02-03 /pmc/articles/PMC2983637/ /pubmed/21580290 http://dx.doi.org/10.1107/S1600536810003661 Text en © Ebenezer and Muthiah 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ebenezer, Samuel
Muthiah, Packianathan Thomas
2-Amino-4,6-dimethyl­pyrimidine–anthranilic acid (1/1)
title 2-Amino-4,6-dimethyl­pyrimidine–anthranilic acid (1/1)
title_full 2-Amino-4,6-dimethyl­pyrimidine–anthranilic acid (1/1)
title_fullStr 2-Amino-4,6-dimethyl­pyrimidine–anthranilic acid (1/1)
title_full_unstemmed 2-Amino-4,6-dimethyl­pyrimidine–anthranilic acid (1/1)
title_short 2-Amino-4,6-dimethyl­pyrimidine–anthranilic acid (1/1)
title_sort 2-amino-4,6-dimethyl­pyrimidine–anthranilic acid (1/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983637/
https://www.ncbi.nlm.nih.gov/pubmed/21580290
http://dx.doi.org/10.1107/S1600536810003661
work_keys_str_mv AT ebenezersamuel 2amino46dimethylpyrimidineanthranilicacid11
AT muthiahpackianathanthomas 2amino46dimethylpyrimidineanthranilicacid11

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