[(1R)-3-Benzoyl-1,7,7-trimethyl­bicyclo­[2.2.1]heptan-2-onato-κ(2) O,O′]chlorido(η(6)-p-cymene)ruthenium(II)

The asymmetric unit of the title compound, [RuCl(C(10)H(14))(C(17)H(19)O(2))], contains two diastereomers. In both, the Ru(II) ion has a tetra­hedral coordination, formed by two O atoms of the camphor-derived ligand and the p-cymene and Cl ligands. In the crystal structure, weak inter­molecular C—H⋯...

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Detalles Bibliográficos
Autores principales: Harrad, Mohamed Anouar, Valerga, Pedro, Puerta, M. Carmen, Ali, Mustapha Ait, El Firdoussi, Larbi, Karim, Abdellah
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983648/
https://www.ncbi.nlm.nih.gov/pubmed/21580227
http://dx.doi.org/10.1107/S1600536810005015
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author Harrad, Mohamed Anouar
Valerga, Pedro
Puerta, M. Carmen
Ali, Mustapha Ait
El Firdoussi, Larbi
Karim, Abdellah
author_facet Harrad, Mohamed Anouar
Valerga, Pedro
Puerta, M. Carmen
Ali, Mustapha Ait
El Firdoussi, Larbi
Karim, Abdellah
author_sort Harrad, Mohamed Anouar
collection PubMed
description The asymmetric unit of the title compound, [RuCl(C(10)H(14))(C(17)H(19)O(2))], contains two diastereomers. In both, the Ru(II) ion has a tetra­hedral coordination, formed by two O atoms of the camphor-derived ligand and the p-cymene and Cl ligands. In the crystal structure, weak inter­molecular C—H⋯Cl inter­actions link the mol­ecules into columns propagated along [010].
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spelling pubmed-29836482010-12-30 [(1R)-3-Benzoyl-1,7,7-trimethyl­bicyclo­[2.2.1]heptan-2-onato-κ(2) O,O′]chlorido(η(6)-p-cymene)ruthenium(II) Harrad, Mohamed Anouar Valerga, Pedro Puerta, M. Carmen Ali, Mustapha Ait El Firdoussi, Larbi Karim, Abdellah Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [RuCl(C(10)H(14))(C(17)H(19)O(2))], contains two diastereomers. In both, the Ru(II) ion has a tetra­hedral coordination, formed by two O atoms of the camphor-derived ligand and the p-cymene and Cl ligands. In the crystal structure, weak inter­molecular C—H⋯Cl inter­actions link the mol­ecules into columns propagated along [010]. International Union of Crystallography 2010-02-13 /pmc/articles/PMC2983648/ /pubmed/21580227 http://dx.doi.org/10.1107/S1600536810005015 Text en © Harrad et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Harrad, Mohamed Anouar
Valerga, Pedro
Puerta, M. Carmen
Ali, Mustapha Ait
El Firdoussi, Larbi
Karim, Abdellah
[(1R)-3-Benzoyl-1,7,7-trimethyl­bicyclo­[2.2.1]heptan-2-onato-κ(2) O,O′]chlorido(η(6)-p-cymene)ruthenium(II)
title [(1R)-3-Benzoyl-1,7,7-trimethyl­bicyclo­[2.2.1]heptan-2-onato-κ(2) O,O′]chlorido(η(6)-p-cymene)ruthenium(II)
title_full [(1R)-3-Benzoyl-1,7,7-trimethyl­bicyclo­[2.2.1]heptan-2-onato-κ(2) O,O′]chlorido(η(6)-p-cymene)ruthenium(II)
title_fullStr [(1R)-3-Benzoyl-1,7,7-trimethyl­bicyclo­[2.2.1]heptan-2-onato-κ(2) O,O′]chlorido(η(6)-p-cymene)ruthenium(II)
title_full_unstemmed [(1R)-3-Benzoyl-1,7,7-trimethyl­bicyclo­[2.2.1]heptan-2-onato-κ(2) O,O′]chlorido(η(6)-p-cymene)ruthenium(II)
title_short [(1R)-3-Benzoyl-1,7,7-trimethyl­bicyclo­[2.2.1]heptan-2-onato-κ(2) O,O′]chlorido(η(6)-p-cymene)ruthenium(II)
title_sort [(1r)-3-benzoyl-1,7,7-trimethyl­bicyclo­[2.2.1]heptan-2-onato-κ(2) o,o′]chlorido(η(6)-p-cymene)ruthenium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983648/
https://www.ncbi.nlm.nih.gov/pubmed/21580227
http://dx.doi.org/10.1107/S1600536810005015
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