7-Chloro-4-[(E)-2-(4-methoxy­benzyl­idene)hydrazin-1-yl]quinoline monohydrate

The organic mol­ecule in the title hydrate, C(17)H(14)ClN(3)O·H(2)O, has a small but significant twist from planarity, as seen in the dihedral angle of 12.10 (17)° between the quinoline and benzene rings. The conformation about the C=N bond is E. Chains along the b axis are formed in the crystal str...

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Detalles Bibliográficos
Autores principales: de Lima Ferreira, Marcelle, de Souza, Marcus V. N., Howie, R. Alan, Tiekink, Edward R. T., Wardell, James L., Wardell, Solange M. S. V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983656/
https://www.ncbi.nlm.nih.gov/pubmed/21580437
http://dx.doi.org/10.1107/S1600536810006598
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author de Lima Ferreira, Marcelle
de Souza, Marcus V. N.
Howie, R. Alan
Tiekink, Edward R. T.
Wardell, James L.
Wardell, Solange M. S. V.
author_facet de Lima Ferreira, Marcelle
de Souza, Marcus V. N.
Howie, R. Alan
Tiekink, Edward R. T.
Wardell, James L.
Wardell, Solange M. S. V.
author_sort de Lima Ferreira, Marcelle
collection PubMed
description The organic mol­ecule in the title hydrate, C(17)H(14)ClN(3)O·H(2)O, has a small but significant twist from planarity, as seen in the dihedral angle of 12.10 (17)° between the quinoline and benzene rings. The conformation about the C=N bond is E. Chains along the b axis are formed in the crystal structure aided by water–quinoline O—H⋯N (× 2) and hydrazone–water N—H⋯O hydrogen bonds. Layers of these chains stack along the a axis via C—H⋯π and π–π inter­actions [ring centroid–ring centroid distance = 3.674 (2) Å]. C—H⋯O inter­actions are also present.
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spelling pubmed-29836562010-12-30 7-Chloro-4-[(E)-2-(4-methoxy­benzyl­idene)hydrazin-1-yl]quinoline monohydrate de Lima Ferreira, Marcelle de Souza, Marcus V. N. Howie, R. Alan Tiekink, Edward R. T. Wardell, James L. Wardell, Solange M. S. V. Acta Crystallogr Sect E Struct Rep Online Organic Papers The organic mol­ecule in the title hydrate, C(17)H(14)ClN(3)O·H(2)O, has a small but significant twist from planarity, as seen in the dihedral angle of 12.10 (17)° between the quinoline and benzene rings. The conformation about the C=N bond is E. Chains along the b axis are formed in the crystal structure aided by water–quinoline O—H⋯N (× 2) and hydrazone–water N—H⋯O hydrogen bonds. Layers of these chains stack along the a axis via C—H⋯π and π–π inter­actions [ring centroid–ring centroid distance = 3.674 (2) Å]. C—H⋯O inter­actions are also present. International Union of Crystallography 2010-02-27 /pmc/articles/PMC2983656/ /pubmed/21580437 http://dx.doi.org/10.1107/S1600536810006598 Text en © Lima Ferreira et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
de Lima Ferreira, Marcelle
de Souza, Marcus V. N.
Howie, R. Alan
Tiekink, Edward R. T.
Wardell, James L.
Wardell, Solange M. S. V.
7-Chloro-4-[(E)-2-(4-methoxy­benzyl­idene)hydrazin-1-yl]quinoline monohydrate
title 7-Chloro-4-[(E)-2-(4-methoxy­benzyl­idene)hydrazin-1-yl]quinoline monohydrate
title_full 7-Chloro-4-[(E)-2-(4-methoxy­benzyl­idene)hydrazin-1-yl]quinoline monohydrate
title_fullStr 7-Chloro-4-[(E)-2-(4-methoxy­benzyl­idene)hydrazin-1-yl]quinoline monohydrate
title_full_unstemmed 7-Chloro-4-[(E)-2-(4-methoxy­benzyl­idene)hydrazin-1-yl]quinoline monohydrate
title_short 7-Chloro-4-[(E)-2-(4-methoxy­benzyl­idene)hydrazin-1-yl]quinoline monohydrate
title_sort 7-chloro-4-[(e)-2-(4-methoxy­benzyl­idene)hydrazin-1-yl]quinoline monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983656/
https://www.ncbi.nlm.nih.gov/pubmed/21580437
http://dx.doi.org/10.1107/S1600536810006598
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