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trans-Chlorido(dimethyl sulfoxide-κS)(pyridine-2-carboxylato-κ(2) N,O)platinum(II)
In the title complex, [Pt(C(6)H(4)NO(2))Cl(C(2)H(6)OS)], the Pt(II) ion is in a distorted square-planar environment defined by the N and O atoms from the chelating pyridine-2-carboxylate (pic) anionic ligand, one S atom of the dimethyl sulfoxide molecule and one Cl ion. The complex is disposed abo...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983664/ https://www.ncbi.nlm.nih.gov/pubmed/21580240 http://dx.doi.org/10.1107/S1600536810005520 |
Sumario: | In the title complex, [Pt(C(6)H(4)NO(2))Cl(C(2)H(6)OS)], the Pt(II) ion is in a distorted square-planar environment defined by the N and O atoms from the chelating pyridine-2-carboxylate (pic) anionic ligand, one S atom of the dimethyl sulfoxide molecule and one Cl ion. The complex is disposed about a crystallographic mirror plane parallel to the ac plane passing through all the atoms of the complex except the methyl atoms of the dimethyl sulfoxide. The molecules are stacked in columns along the b axis with a Pt⋯Pt distance of 4.9508 (5) Å. Within the column, intermolecular C—H⋯O hydrogen bonds and weak π–π interactions between adjacent pyridine rings are present, the shortest centroid–centroid distance being 5.153 (4) Å. |
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