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trans-Chlorido(dimethyl sulfoxide-κS)(pyridine-2-carboxyl­ato-κ(2) N,O)platinum(II)

In the title complex, [Pt(C(6)H(4)NO(2))Cl(C(2)H(6)OS)], the Pt(II) ion is in a distorted square-planar environment defined by the N and O atoms from the chelating pyridine-2-carboxyl­ate (pic) anionic ligand, one S atom of the dimethyl sulfoxide mol­ecule and one Cl ion. The complex is disposed abo...

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Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983664/
https://www.ncbi.nlm.nih.gov/pubmed/21580240
http://dx.doi.org/10.1107/S1600536810005520
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author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description In the title complex, [Pt(C(6)H(4)NO(2))Cl(C(2)H(6)OS)], the Pt(II) ion is in a distorted square-planar environment defined by the N and O atoms from the chelating pyridine-2-carboxyl­ate (pic) anionic ligand, one S atom of the dimethyl sulfoxide mol­ecule and one Cl ion. The complex is disposed about a crystallographic mirror plane parallel to the ac plane passing through all the atoms of the complex except the methyl atoms of the dimethyl sulfoxide. The mol­ecules are stacked in columns along the b axis with a Pt⋯Pt distance of 4.9508 (5) Å. Within the column, inter­molecular C—H⋯O hydrogen bonds and weak π–π inter­actions between adjacent pyridine rings are present, the shortest centroid–centroid distance being 5.153 (4) Å.
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spelling pubmed-29836642010-12-30 trans-Chlorido(dimethyl sulfoxide-κS)(pyridine-2-carboxyl­ato-κ(2) N,O)platinum(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Pt(C(6)H(4)NO(2))Cl(C(2)H(6)OS)], the Pt(II) ion is in a distorted square-planar environment defined by the N and O atoms from the chelating pyridine-2-carboxyl­ate (pic) anionic ligand, one S atom of the dimethyl sulfoxide mol­ecule and one Cl ion. The complex is disposed about a crystallographic mirror plane parallel to the ac plane passing through all the atoms of the complex except the methyl atoms of the dimethyl sulfoxide. The mol­ecules are stacked in columns along the b axis with a Pt⋯Pt distance of 4.9508 (5) Å. Within the column, inter­molecular C—H⋯O hydrogen bonds and weak π–π inter­actions between adjacent pyridine rings are present, the shortest centroid–centroid distance being 5.153 (4) Å. International Union of Crystallography 2010-02-13 /pmc/articles/PMC2983664/ /pubmed/21580240 http://dx.doi.org/10.1107/S1600536810005520 Text en © Kwang Ha 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
trans-Chlorido(dimethyl sulfoxide-κS)(pyridine-2-carboxyl­ato-κ(2) N,O)platinum(II)
title trans-Chlorido(dimethyl sulfoxide-κS)(pyridine-2-carboxyl­ato-κ(2) N,O)platinum(II)
title_full trans-Chlorido(dimethyl sulfoxide-κS)(pyridine-2-carboxyl­ato-κ(2) N,O)platinum(II)
title_fullStr trans-Chlorido(dimethyl sulfoxide-κS)(pyridine-2-carboxyl­ato-κ(2) N,O)platinum(II)
title_full_unstemmed trans-Chlorido(dimethyl sulfoxide-κS)(pyridine-2-carboxyl­ato-κ(2) N,O)platinum(II)
title_short trans-Chlorido(dimethyl sulfoxide-κS)(pyridine-2-carboxyl­ato-κ(2) N,O)platinum(II)
title_sort trans-chlorido(dimethyl sulfoxide-κs)(pyridine-2-carboxyl­ato-κ(2) n,o)platinum(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983664/
https://www.ncbi.nlm.nih.gov/pubmed/21580240
http://dx.doi.org/10.1107/S1600536810005520
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