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trans-Chlorido(dimethyl sulfoxide-κS)(pyridine-2-carboxylato-κ(2) N,O)platinum(II)
In the title complex, [Pt(C(6)H(4)NO(2))Cl(C(2)H(6)OS)], the Pt(II) ion is in a distorted square-planar environment defined by the N and O atoms from the chelating pyridine-2-carboxylate (pic) anionic ligand, one S atom of the dimethyl sulfoxide molecule and one Cl ion. The complex is disposed abo...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983664/ https://www.ncbi.nlm.nih.gov/pubmed/21580240 http://dx.doi.org/10.1107/S1600536810005520 |
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author | Ha, Kwang |
author_facet | Ha, Kwang |
author_sort | Ha, Kwang |
collection | PubMed |
description | In the title complex, [Pt(C(6)H(4)NO(2))Cl(C(2)H(6)OS)], the Pt(II) ion is in a distorted square-planar environment defined by the N and O atoms from the chelating pyridine-2-carboxylate (pic) anionic ligand, one S atom of the dimethyl sulfoxide molecule and one Cl ion. The complex is disposed about a crystallographic mirror plane parallel to the ac plane passing through all the atoms of the complex except the methyl atoms of the dimethyl sulfoxide. The molecules are stacked in columns along the b axis with a Pt⋯Pt distance of 4.9508 (5) Å. Within the column, intermolecular C—H⋯O hydrogen bonds and weak π–π interactions between adjacent pyridine rings are present, the shortest centroid–centroid distance being 5.153 (4) Å. |
format | Text |
id | pubmed-2983664 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29836642010-12-30 trans-Chlorido(dimethyl sulfoxide-κS)(pyridine-2-carboxylato-κ(2) N,O)platinum(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Pt(C(6)H(4)NO(2))Cl(C(2)H(6)OS)], the Pt(II) ion is in a distorted square-planar environment defined by the N and O atoms from the chelating pyridine-2-carboxylate (pic) anionic ligand, one S atom of the dimethyl sulfoxide molecule and one Cl ion. The complex is disposed about a crystallographic mirror plane parallel to the ac plane passing through all the atoms of the complex except the methyl atoms of the dimethyl sulfoxide. The molecules are stacked in columns along the b axis with a Pt⋯Pt distance of 4.9508 (5) Å. Within the column, intermolecular C—H⋯O hydrogen bonds and weak π–π interactions between adjacent pyridine rings are present, the shortest centroid–centroid distance being 5.153 (4) Å. International Union of Crystallography 2010-02-13 /pmc/articles/PMC2983664/ /pubmed/21580240 http://dx.doi.org/10.1107/S1600536810005520 Text en © Kwang Ha 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ha, Kwang trans-Chlorido(dimethyl sulfoxide-κS)(pyridine-2-carboxylato-κ(2) N,O)platinum(II) |
title |
trans-Chlorido(dimethyl sulfoxide-κS)(pyridine-2-carboxylato-κ(2)
N,O)platinum(II) |
title_full |
trans-Chlorido(dimethyl sulfoxide-κS)(pyridine-2-carboxylato-κ(2)
N,O)platinum(II) |
title_fullStr |
trans-Chlorido(dimethyl sulfoxide-κS)(pyridine-2-carboxylato-κ(2)
N,O)platinum(II) |
title_full_unstemmed |
trans-Chlorido(dimethyl sulfoxide-κS)(pyridine-2-carboxylato-κ(2)
N,O)platinum(II) |
title_short |
trans-Chlorido(dimethyl sulfoxide-κS)(pyridine-2-carboxylato-κ(2)
N,O)platinum(II) |
title_sort | trans-chlorido(dimethyl sulfoxide-κs)(pyridine-2-carboxylato-κ(2)
n,o)platinum(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983664/ https://www.ncbi.nlm.nih.gov/pubmed/21580240 http://dx.doi.org/10.1107/S1600536810005520 |
work_keys_str_mv | AT hakwang transchloridodimethylsulfoxidekspyridine2carboxylatok2noplatinumii |