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trans-Dichlorido(1,4,8,11-tetraazacyclotetradecane)manganese(III) tetrafluoridoborate
In the title manganese(III) complex, [MnCl(2)(C(10)H(24)N(4))]BF(4) or trans-[MnCl(2)(cyclam)]BF(4) (cyclam is the tetradentate amine ligand 1,4,8,11-tetraazacyclotetradecane), the Mn(III) ions occupy the center of a distorted octahedron coordinated by all four ligand nitrogen donors in the m...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983670/ https://www.ncbi.nlm.nih.gov/pubmed/21580217 http://dx.doi.org/10.1107/S1600536810004058 |
Sumario: | In the title manganese(III) complex, [MnCl(2)(C(10)H(24)N(4))]BF(4) or trans-[MnCl(2)(cyclam)]BF(4) (cyclam is the tetradentate amine ligand 1,4,8,11-tetraazacyclotetradecane), the Mn(III) ions occupy the center of a distorted octahedron coordinated by all four ligand nitrogen donors in the macrobicyclic cavity and two chloride ions occupy the axial positions. Intramolecular hydrogen bonding involving the coordinated chloride ions and the hydrogen atoms of the cyclam ligand is observed. Intermolecular hydrogen bonding involving the tetrafluoridoborate anion and hydrogen atoms of the cyclam ligand leads to an infinite one-dimensional chain along the a axis. The tetrafluoridoborate and inorganic units are linked by N—H⋯F hydrogen bonds. The structure may be compared with those of analogous compounds [MnCl(2)(cyclam)]ClO(4) and [Mn(CN)(2)(cyclam)]ClO(4). |
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