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trans-Dichlorido(1,4,8,11-tetraazacyclotetradecane)manganese(III) tetrafluoridoborate
In the title manganese(III) complex, [MnCl(2)(C(10)H(24)N(4))]BF(4) or trans-[MnCl(2)(cyclam)]BF(4) (cyclam is the tetradentate amine ligand 1,4,8,11-tetraazacyclotetradecane), the Mn(III) ions occupy the center of a distorted octahedron coordinated by all four ligand nitrogen donors in the m...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983670/ https://www.ncbi.nlm.nih.gov/pubmed/21580217 http://dx.doi.org/10.1107/S1600536810004058 |
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author | Zaouali Zgolli, Donia Boughzala, Habib Driss, Ahmed |
author_facet | Zaouali Zgolli, Donia Boughzala, Habib Driss, Ahmed |
author_sort | Zaouali Zgolli, Donia |
collection | PubMed |
description | In the title manganese(III) complex, [MnCl(2)(C(10)H(24)N(4))]BF(4) or trans-[MnCl(2)(cyclam)]BF(4) (cyclam is the tetradentate amine ligand 1,4,8,11-tetraazacyclotetradecane), the Mn(III) ions occupy the center of a distorted octahedron coordinated by all four ligand nitrogen donors in the macrobicyclic cavity and two chloride ions occupy the axial positions. Intramolecular hydrogen bonding involving the coordinated chloride ions and the hydrogen atoms of the cyclam ligand is observed. Intermolecular hydrogen bonding involving the tetrafluoridoborate anion and hydrogen atoms of the cyclam ligand leads to an infinite one-dimensional chain along the a axis. The tetrafluoridoborate and inorganic units are linked by N—H⋯F hydrogen bonds. The structure may be compared with those of analogous compounds [MnCl(2)(cyclam)]ClO(4) and [Mn(CN)(2)(cyclam)]ClO(4). |
format | Text |
id | pubmed-2983670 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29836702010-12-30 trans-Dichlorido(1,4,8,11-tetraazacyclotetradecane)manganese(III) tetrafluoridoborate Zaouali Zgolli, Donia Boughzala, Habib Driss, Ahmed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title manganese(III) complex, [MnCl(2)(C(10)H(24)N(4))]BF(4) or trans-[MnCl(2)(cyclam)]BF(4) (cyclam is the tetradentate amine ligand 1,4,8,11-tetraazacyclotetradecane), the Mn(III) ions occupy the center of a distorted octahedron coordinated by all four ligand nitrogen donors in the macrobicyclic cavity and two chloride ions occupy the axial positions. Intramolecular hydrogen bonding involving the coordinated chloride ions and the hydrogen atoms of the cyclam ligand is observed. Intermolecular hydrogen bonding involving the tetrafluoridoborate anion and hydrogen atoms of the cyclam ligand leads to an infinite one-dimensional chain along the a axis. The tetrafluoridoborate and inorganic units are linked by N—H⋯F hydrogen bonds. The structure may be compared with those of analogous compounds [MnCl(2)(cyclam)]ClO(4) and [Mn(CN)(2)(cyclam)]ClO(4). International Union of Crystallography 2010-02-06 /pmc/articles/PMC2983670/ /pubmed/21580217 http://dx.doi.org/10.1107/S1600536810004058 Text en © Zaouali Zgolli et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zaouali Zgolli, Donia Boughzala, Habib Driss, Ahmed trans-Dichlorido(1,4,8,11-tetraazacyclotetradecane)manganese(III) tetrafluoridoborate |
title |
trans-Dichlorido(1,4,8,11-tetraazacyclotetradecane)manganese(III) tetrafluoridoborate |
title_full |
trans-Dichlorido(1,4,8,11-tetraazacyclotetradecane)manganese(III) tetrafluoridoborate |
title_fullStr |
trans-Dichlorido(1,4,8,11-tetraazacyclotetradecane)manganese(III) tetrafluoridoborate |
title_full_unstemmed |
trans-Dichlorido(1,4,8,11-tetraazacyclotetradecane)manganese(III) tetrafluoridoborate |
title_short |
trans-Dichlorido(1,4,8,11-tetraazacyclotetradecane)manganese(III) tetrafluoridoborate |
title_sort | trans-dichlorido(1,4,8,11-tetraazacyclotetradecane)manganese(iii) tetrafluoridoborate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983670/ https://www.ncbi.nlm.nih.gov/pubmed/21580217 http://dx.doi.org/10.1107/S1600536810004058 |
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