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trans-Dichlorido(1,4,8,11-tetra­azacyclo­tetra­deca­ne)manganese(III) tetra­fluorido­borate

In the title manganese(III) complex, [MnCl(2)(C(10)H(24)N(4))]BF(4) or trans-[MnCl(2)(cyclam)]BF(4) (cyclam is the tetra­dentate amine ligand 1,4,8,11-tetra­azacyclo­tetra­deca­ne), the Mn(III) ions occupy the center of a distorted octa­hedron coordinated by all four ligand nitro­gen donors in the m...

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Detalles Bibliográficos
Autores principales: Zaouali Zgolli, Donia, Boughzala, Habib, Driss, Ahmed
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983670/
https://www.ncbi.nlm.nih.gov/pubmed/21580217
http://dx.doi.org/10.1107/S1600536810004058
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author Zaouali Zgolli, Donia
Boughzala, Habib
Driss, Ahmed
author_facet Zaouali Zgolli, Donia
Boughzala, Habib
Driss, Ahmed
author_sort Zaouali Zgolli, Donia
collection PubMed
description In the title manganese(III) complex, [MnCl(2)(C(10)H(24)N(4))]BF(4) or trans-[MnCl(2)(cyclam)]BF(4) (cyclam is the tetra­dentate amine ligand 1,4,8,11-tetra­azacyclo­tetra­deca­ne), the Mn(III) ions occupy the center of a distorted octa­hedron coordinated by all four ligand nitro­gen donors in the macrobicyclic cavity and two chloride ions occupy the axial positions. Intra­molecular hydrogen bonding involving the coordinated chloride ions and the hydrogen atoms of the cyclam ligand is observed. Inter­molecular hydrogen bonding involving the tetrafluoridoborate anion and hydrogen atoms of the cyclam ligand leads to an infinite one-dimensional chain along the a axis. The tetra­fluoridoborate and inorganic units are linked by N—H⋯F hydrogen bonds. The structure may be compared with those of analogous compounds [MnCl(2)(cyclam)]ClO(4) and [Mn(CN)(2)(cyclam)]ClO(4).
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spelling pubmed-29836702010-12-30 trans-Dichlorido(1,4,8,11-tetra­azacyclo­tetra­deca­ne)manganese(III) tetra­fluorido­borate Zaouali Zgolli, Donia Boughzala, Habib Driss, Ahmed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title manganese(III) complex, [MnCl(2)(C(10)H(24)N(4))]BF(4) or trans-[MnCl(2)(cyclam)]BF(4) (cyclam is the tetra­dentate amine ligand 1,4,8,11-tetra­azacyclo­tetra­deca­ne), the Mn(III) ions occupy the center of a distorted octa­hedron coordinated by all four ligand nitro­gen donors in the macrobicyclic cavity and two chloride ions occupy the axial positions. Intra­molecular hydrogen bonding involving the coordinated chloride ions and the hydrogen atoms of the cyclam ligand is observed. Inter­molecular hydrogen bonding involving the tetrafluoridoborate anion and hydrogen atoms of the cyclam ligand leads to an infinite one-dimensional chain along the a axis. The tetra­fluoridoborate and inorganic units are linked by N—H⋯F hydrogen bonds. The structure may be compared with those of analogous compounds [MnCl(2)(cyclam)]ClO(4) and [Mn(CN)(2)(cyclam)]ClO(4). International Union of Crystallography 2010-02-06 /pmc/articles/PMC2983670/ /pubmed/21580217 http://dx.doi.org/10.1107/S1600536810004058 Text en © Zaouali Zgolli et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zaouali Zgolli, Donia
Boughzala, Habib
Driss, Ahmed
trans-Dichlorido(1,4,8,11-tetra­azacyclo­tetra­deca­ne)manganese(III) tetra­fluorido­borate
title trans-Dichlorido(1,4,8,11-tetra­azacyclo­tetra­deca­ne)manganese(III) tetra­fluorido­borate
title_full trans-Dichlorido(1,4,8,11-tetra­azacyclo­tetra­deca­ne)manganese(III) tetra­fluorido­borate
title_fullStr trans-Dichlorido(1,4,8,11-tetra­azacyclo­tetra­deca­ne)manganese(III) tetra­fluorido­borate
title_full_unstemmed trans-Dichlorido(1,4,8,11-tetra­azacyclo­tetra­deca­ne)manganese(III) tetra­fluorido­borate
title_short trans-Dichlorido(1,4,8,11-tetra­azacyclo­tetra­deca­ne)manganese(III) tetra­fluorido­borate
title_sort trans-dichlorido(1,4,8,11-tetra­azacyclo­tetra­deca­ne)manganese(iii) tetra­fluorido­borate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983670/
https://www.ncbi.nlm.nih.gov/pubmed/21580217
http://dx.doi.org/10.1107/S1600536810004058
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