3,5-Bis(3-methyl­imidazolium-1-ylmeth­yl)toluene bis­(hexa­fluoro­phosphate)

The asymmetric unit of the title N-heterocyclic carbene compound, C(17)H(22)N(4) (2+)·2PF(6) (−), consists of one N-heterocyclic carbene dication and two hexa­fluoro­phosphate anions. The two imidazole rings are twisted away from but to the same side of the central toluene ring, making dihedral angl...

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Detalles Bibliográficos
Autores principales: Washeel, Abbas, Haque, Rosenani A., Teoh, Siang Guan, Yeap, Chin Sing, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983672/
https://www.ncbi.nlm.nih.gov/pubmed/21580325
http://dx.doi.org/10.1107/S1600536810003739
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author Washeel, Abbas
Haque, Rosenani A.
Teoh, Siang Guan
Yeap, Chin Sing
Fun, Hoong-Kun
author_facet Washeel, Abbas
Haque, Rosenani A.
Teoh, Siang Guan
Yeap, Chin Sing
Fun, Hoong-Kun
author_sort Washeel, Abbas
collection PubMed
description The asymmetric unit of the title N-heterocyclic carbene compound, C(17)H(22)N(4) (2+)·2PF(6) (−), consists of one N-heterocyclic carbene dication and two hexa­fluoro­phosphate anions. The two imidazole rings are twisted away from but to the same side of the central toluene ring, making dihedral angles of 76.69 (7) and 78.03 (7)° with the central ring. In the crystal, the components are linked by C—H⋯F interactions, generating a three-dimensional network.
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spelling pubmed-29836722010-12-30 3,5-Bis(3-methyl­imidazolium-1-ylmeth­yl)toluene bis­(hexa­fluoro­phosphate) Washeel, Abbas Haque, Rosenani A. Teoh, Siang Guan Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title N-heterocyclic carbene compound, C(17)H(22)N(4) (2+)·2PF(6) (−), consists of one N-heterocyclic carbene dication and two hexa­fluoro­phosphate anions. The two imidazole rings are twisted away from but to the same side of the central toluene ring, making dihedral angles of 76.69 (7) and 78.03 (7)° with the central ring. In the crystal, the components are linked by C—H⋯F interactions, generating a three-dimensional network. International Union of Crystallography 2010-02-06 /pmc/articles/PMC2983672/ /pubmed/21580325 http://dx.doi.org/10.1107/S1600536810003739 Text en © Washeel et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Washeel, Abbas
Haque, Rosenani A.
Teoh, Siang Guan
Yeap, Chin Sing
Fun, Hoong-Kun
3,5-Bis(3-methyl­imidazolium-1-ylmeth­yl)toluene bis­(hexa­fluoro­phosphate)
title 3,5-Bis(3-methyl­imidazolium-1-ylmeth­yl)toluene bis­(hexa­fluoro­phosphate)
title_full 3,5-Bis(3-methyl­imidazolium-1-ylmeth­yl)toluene bis­(hexa­fluoro­phosphate)
title_fullStr 3,5-Bis(3-methyl­imidazolium-1-ylmeth­yl)toluene bis­(hexa­fluoro­phosphate)
title_full_unstemmed 3,5-Bis(3-methyl­imidazolium-1-ylmeth­yl)toluene bis­(hexa­fluoro­phosphate)
title_short 3,5-Bis(3-methyl­imidazolium-1-ylmeth­yl)toluene bis­(hexa­fluoro­phosphate)
title_sort 3,5-bis(3-methyl­imidazolium-1-ylmeth­yl)toluene bis­(hexa­fluoro­phosphate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983672/
https://www.ncbi.nlm.nih.gov/pubmed/21580325
http://dx.doi.org/10.1107/S1600536810003739
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