Dichlorido(2,4,6-tri-2-pyridyl-1,3,5-triazine)manganese(II)

In the title complex, [MnCl(2)(C(18)H(12)N(6))], the Mn(II) ion is five-coordinated in an approximately square-pyramidal geometry defined by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and two Cl atoms. In the crystal, the mol­ecules are stacked in columns along the c a...

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Autor principal: Ha, Kwang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983677/
https://www.ncbi.nlm.nih.gov/pubmed/21580215
http://dx.doi.org/10.1107/S1600536810004204
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author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description In the title complex, [MnCl(2)(C(18)H(12)N(6))], the Mn(II) ion is five-coordinated in an approximately square-pyramidal geometry defined by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and two Cl atoms. In the crystal, the mol­ecules are stacked in columns along the c axis and display inter­molecular π–π inter­actions between the six-membered rings, the shortest centroid–centroid distance being 3.553 (3)Å. Inter­molecular C—H⋯Cl contacts are also noted.
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spelling pubmed-29836772010-12-30 Dichlorido(2,4,6-tri-2-pyridyl-1,3,5-triazine)manganese(II) Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [MnCl(2)(C(18)H(12)N(6))], the Mn(II) ion is five-coordinated in an approximately square-pyramidal geometry defined by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and two Cl atoms. In the crystal, the mol­ecules are stacked in columns along the c axis and display inter­molecular π–π inter­actions between the six-membered rings, the shortest centroid–centroid distance being 3.553 (3)Å. Inter­molecular C—H⋯Cl contacts are also noted. International Union of Crystallography 2010-02-06 /pmc/articles/PMC2983677/ /pubmed/21580215 http://dx.doi.org/10.1107/S1600536810004204 Text en © Kwang Ha 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
Dichlorido(2,4,6-tri-2-pyridyl-1,3,5-triazine)manganese(II)
title Dichlorido(2,4,6-tri-2-pyridyl-1,3,5-triazine)manganese(II)
title_full Dichlorido(2,4,6-tri-2-pyridyl-1,3,5-triazine)manganese(II)
title_fullStr Dichlorido(2,4,6-tri-2-pyridyl-1,3,5-triazine)manganese(II)
title_full_unstemmed Dichlorido(2,4,6-tri-2-pyridyl-1,3,5-triazine)manganese(II)
title_short Dichlorido(2,4,6-tri-2-pyridyl-1,3,5-triazine)manganese(II)
title_sort dichlorido(2,4,6-tri-2-pyridyl-1,3,5-triazine)manganese(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983677/
https://www.ncbi.nlm.nih.gov/pubmed/21580215
http://dx.doi.org/10.1107/S1600536810004204
work_keys_str_mv AT hakwang dichlorido246tri2pyridyl135triazinemanganeseii

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