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3,3′-Di-tert-butyl-1,1′-[1,3-phenylenebis(methylene)]diurea
The title compound, C(18)H(30)N(4)O(2), contains two tert-butyl urea groups, each connected to a benzene ring though a methylene group. One of the groups occupies a position almost normal to the aromatic plane with a C—N—C—C torsion angle of −94.4 (4)°, while the other is considerably twisted from...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983681/ https://www.ncbi.nlm.nih.gov/pubmed/21580407 http://dx.doi.org/10.1107/S1600536810005866 |
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author | Saeed, Musabbir A. Fronczek, Frank R. Hossain, Md. Alamgir |
author_facet | Saeed, Musabbir A. Fronczek, Frank R. Hossain, Md. Alamgir |
author_sort | Saeed, Musabbir A. |
collection | PubMed |
description | The title compound, C(18)H(30)N(4)O(2), contains two tert-butyl urea groups, each connected to a benzene ring though a methylene group. One of the groups occupies a position almost normal to the aromatic plane with a C—N—C—C torsion angle of −94.4 (4)°, while the other is considerably twisted from the ring with a C—N—C—C torsion angle of −136.1 (4)°. In the crystal, pairs of molecules are connected to each other, forming centrosymmetric dimers in which two NH groups of one molecule act as hydrogen-bond donors to one carbonyl O atom of the other molecule. The dimers are linked into sheets parallel to (100) by N—H⋯O hydrogen bonds involving the remaining N—H and C=O groups. |
format | Text |
id | pubmed-2983681 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29836812010-12-30 3,3′-Di-tert-butyl-1,1′-[1,3-phenylenebis(methylene)]diurea Saeed, Musabbir A. Fronczek, Frank R. Hossain, Md. Alamgir Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(18)H(30)N(4)O(2), contains two tert-butyl urea groups, each connected to a benzene ring though a methylene group. One of the groups occupies a position almost normal to the aromatic plane with a C—N—C—C torsion angle of −94.4 (4)°, while the other is considerably twisted from the ring with a C—N—C—C torsion angle of −136.1 (4)°. In the crystal, pairs of molecules are connected to each other, forming centrosymmetric dimers in which two NH groups of one molecule act as hydrogen-bond donors to one carbonyl O atom of the other molecule. The dimers are linked into sheets parallel to (100) by N—H⋯O hydrogen bonds involving the remaining N—H and C=O groups. International Union of Crystallography 2010-02-20 /pmc/articles/PMC2983681/ /pubmed/21580407 http://dx.doi.org/10.1107/S1600536810005866 Text en © Saeed et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Saeed, Musabbir A. Fronczek, Frank R. Hossain, Md. Alamgir 3,3′-Di-tert-butyl-1,1′-[1,3-phenylenebis(methylene)]diurea |
title | 3,3′-Di-tert-butyl-1,1′-[1,3-phenylenebis(methylene)]diurea |
title_full | 3,3′-Di-tert-butyl-1,1′-[1,3-phenylenebis(methylene)]diurea |
title_fullStr | 3,3′-Di-tert-butyl-1,1′-[1,3-phenylenebis(methylene)]diurea |
title_full_unstemmed | 3,3′-Di-tert-butyl-1,1′-[1,3-phenylenebis(methylene)]diurea |
title_short | 3,3′-Di-tert-butyl-1,1′-[1,3-phenylenebis(methylene)]diurea |
title_sort | 3,3′-di-tert-butyl-1,1′-[1,3-phenylenebis(methylene)]diurea |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983681/ https://www.ncbi.nlm.nih.gov/pubmed/21580407 http://dx.doi.org/10.1107/S1600536810005866 |
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