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3,3′-Di-tert-butyl-1,1′-[1,3-phenyl­enebis(methyl­ene)]diurea

The title compound, C(18)H(30)N(4)O(2), contains two tert-butyl urea groups, each connected to a benzene ring though a methyl­ene group. One of the groups occupies a position almost normal to the aromatic plane with a C—N—C—C torsion angle of −94.4 (4)°, while the other is considerably twisted from...

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Detalles Bibliográficos
Autores principales: Saeed, Musabbir A., Fronczek, Frank R., Hossain, Md. Alamgir
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983681/
https://www.ncbi.nlm.nih.gov/pubmed/21580407
http://dx.doi.org/10.1107/S1600536810005866
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author Saeed, Musabbir A.
Fronczek, Frank R.
Hossain, Md. Alamgir
author_facet Saeed, Musabbir A.
Fronczek, Frank R.
Hossain, Md. Alamgir
author_sort Saeed, Musabbir A.
collection PubMed
description The title compound, C(18)H(30)N(4)O(2), contains two tert-butyl urea groups, each connected to a benzene ring though a methyl­ene group. One of the groups occupies a position almost normal to the aromatic plane with a C—N—C—C torsion angle of −94.4 (4)°, while the other is considerably twisted from the ring with a C—N—C—C torsion angle of −136.1 (4)°. In the crystal, pairs of mol­ecules are connected to each other, forming centrosymmetric dimers in which two NH groups of one mol­ecule act as hydrogen-bond donors to one carbonyl O atom of the other mol­ecule. The dimers are linked into sheets parallel to (100) by N—H⋯O hydrogen bonds involving the remaining N—H and C=O groups.
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spelling pubmed-29836812010-12-30 3,3′-Di-tert-butyl-1,1′-[1,3-phenyl­enebis(methyl­ene)]diurea Saeed, Musabbir A. Fronczek, Frank R. Hossain, Md. Alamgir Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(18)H(30)N(4)O(2), contains two tert-butyl urea groups, each connected to a benzene ring though a methyl­ene group. One of the groups occupies a position almost normal to the aromatic plane with a C—N—C—C torsion angle of −94.4 (4)°, while the other is considerably twisted from the ring with a C—N—C—C torsion angle of −136.1 (4)°. In the crystal, pairs of mol­ecules are connected to each other, forming centrosymmetric dimers in which two NH groups of one mol­ecule act as hydrogen-bond donors to one carbonyl O atom of the other mol­ecule. The dimers are linked into sheets parallel to (100) by N—H⋯O hydrogen bonds involving the remaining N—H and C=O groups. International Union of Crystallography 2010-02-20 /pmc/articles/PMC2983681/ /pubmed/21580407 http://dx.doi.org/10.1107/S1600536810005866 Text en © Saeed et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Saeed, Musabbir A.
Fronczek, Frank R.
Hossain, Md. Alamgir
3,3′-Di-tert-butyl-1,1′-[1,3-phenyl­enebis(methyl­ene)]diurea
title 3,3′-Di-tert-butyl-1,1′-[1,3-phenyl­enebis(methyl­ene)]diurea
title_full 3,3′-Di-tert-butyl-1,1′-[1,3-phenyl­enebis(methyl­ene)]diurea
title_fullStr 3,3′-Di-tert-butyl-1,1′-[1,3-phenyl­enebis(methyl­ene)]diurea
title_full_unstemmed 3,3′-Di-tert-butyl-1,1′-[1,3-phenyl­enebis(methyl­ene)]diurea
title_short 3,3′-Di-tert-butyl-1,1′-[1,3-phenyl­enebis(methyl­ene)]diurea
title_sort 3,3′-di-tert-butyl-1,1′-[1,3-phenyl­enebis(methyl­ene)]diurea
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983681/
https://www.ncbi.nlm.nih.gov/pubmed/21580407
http://dx.doi.org/10.1107/S1600536810005866
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