Ethyl [1-(4-bromo­phen­yl)-1-hydr­oxy-3-oxobut­yl](phen­yl)phosphinate monohydrate

In the title hydrate, C(18)H(20)BrO(4)P·H(2)O, a staggered conformation is found when the organic mol­ecule is viewed down the central P—C bond, with the oxo and hydroxyl groups being diagonally opposite; each of the central P and C atoms has an S-configuration. The crystal structure features supra­...

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Detalles Bibliográficos
Autores principales: Samanta, Sampak, Perera, Sandun, Broker, Grant A., Zhao, Cong-Gui, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983684/
https://www.ncbi.nlm.nih.gov/pubmed/21580337
http://dx.doi.org/10.1107/S160053681000437X
Descripción
Sumario:In the title hydrate, C(18)H(20)BrO(4)P·H(2)O, a staggered conformation is found when the organic mol­ecule is viewed down the central P—C bond, with the oxo and hydroxyl groups being diagonally opposite; each of the central P and C atoms has an S-configuration. The crystal structure features supra­molecular double chains along the b axis mediated by O(hydrox­yl)–H⋯O(oxo), O(water)–H⋯O(oxo), and O(water)–H⋯O(water) hydrogen bonds.

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