Ethyl [1-(4-bromo­phen­yl)-1-hydr­oxy-3-oxobut­yl](phen­yl)phosphinate monohydrate

In the title hydrate, C(18)H(20)BrO(4)P·H(2)O, a staggered conformation is found when the organic mol­ecule is viewed down the central P—C bond, with the oxo and hydroxyl groups being diagonally opposite; each of the central P and C atoms has an S-configuration. The crystal structure features supra­...

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Detalles Bibliográficos
Autores principales: Samanta, Sampak, Perera, Sandun, Broker, Grant A., Zhao, Cong-Gui, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983684/
https://www.ncbi.nlm.nih.gov/pubmed/21580337
http://dx.doi.org/10.1107/S160053681000437X
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author Samanta, Sampak
Perera, Sandun
Broker, Grant A.
Zhao, Cong-Gui
Tiekink, Edward R. T.
author_facet Samanta, Sampak
Perera, Sandun
Broker, Grant A.
Zhao, Cong-Gui
Tiekink, Edward R. T.
author_sort Samanta, Sampak
collection PubMed
description In the title hydrate, C(18)H(20)BrO(4)P·H(2)O, a staggered conformation is found when the organic mol­ecule is viewed down the central P—C bond, with the oxo and hydroxyl groups being diagonally opposite; each of the central P and C atoms has an S-configuration. The crystal structure features supra­molecular double chains along the b axis mediated by O(hydrox­yl)–H⋯O(oxo), O(water)–H⋯O(oxo), and O(water)–H⋯O(water) hydrogen bonds.
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spelling pubmed-29836842010-12-30 Ethyl [1-(4-bromo­phen­yl)-1-hydr­oxy-3-oxobut­yl](phen­yl)phosphinate monohydrate Samanta, Sampak Perera, Sandun Broker, Grant A. Zhao, Cong-Gui Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title hydrate, C(18)H(20)BrO(4)P·H(2)O, a staggered conformation is found when the organic mol­ecule is viewed down the central P—C bond, with the oxo and hydroxyl groups being diagonally opposite; each of the central P and C atoms has an S-configuration. The crystal structure features supra­molecular double chains along the b axis mediated by O(hydrox­yl)–H⋯O(oxo), O(water)–H⋯O(oxo), and O(water)–H⋯O(water) hydrogen bonds. International Union of Crystallography 2010-02-10 /pmc/articles/PMC2983684/ /pubmed/21580337 http://dx.doi.org/10.1107/S160053681000437X Text en © Samanta et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Samanta, Sampak
Perera, Sandun
Broker, Grant A.
Zhao, Cong-Gui
Tiekink, Edward R. T.
Ethyl [1-(4-bromo­phen­yl)-1-hydr­oxy-3-oxobut­yl](phen­yl)phosphinate monohydrate
title Ethyl [1-(4-bromo­phen­yl)-1-hydr­oxy-3-oxobut­yl](phen­yl)phosphinate monohydrate
title_full Ethyl [1-(4-bromo­phen­yl)-1-hydr­oxy-3-oxobut­yl](phen­yl)phosphinate monohydrate
title_fullStr Ethyl [1-(4-bromo­phen­yl)-1-hydr­oxy-3-oxobut­yl](phen­yl)phosphinate monohydrate
title_full_unstemmed Ethyl [1-(4-bromo­phen­yl)-1-hydr­oxy-3-oxobut­yl](phen­yl)phosphinate monohydrate
title_short Ethyl [1-(4-bromo­phen­yl)-1-hydr­oxy-3-oxobut­yl](phen­yl)phosphinate monohydrate
title_sort ethyl [1-(4-bromo­phen­yl)-1-hydr­oxy-3-oxobut­yl](phen­yl)phosphinate monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983684/
https://www.ncbi.nlm.nih.gov/pubmed/21580337
http://dx.doi.org/10.1107/S160053681000437X
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