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Poly[(μ(2)-4,4′-bipyridine)(μ(2)-3,5-dicarboxybenzenesulfonato)silver(I)]
In the title compound, [Ag(C(8)H(5)O(7)S)(C(10)H(8)N(2))](n), the Ag atom is tetracoordinated by two 4,4′-bipydidine (4,4′-bipy) N atoms and two monodentate sulfonate O atoms of the 5-sulfoisophthalic acid (H(3) sip) ligands. Adjacent Ag atoms are bonded through four sulfonate O atoms, forming a di...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983702/ https://www.ncbi.nlm.nih.gov/pubmed/21580213 http://dx.doi.org/10.1107/S160053681000406X |
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author | Lin, Dan Lian, Ping Xie, Yong-Rong |
author_facet | Lin, Dan Lian, Ping Xie, Yong-Rong |
author_sort | Lin, Dan |
collection | PubMed |
description | In the title compound, [Ag(C(8)H(5)O(7)S)(C(10)H(8)N(2))](n), the Ag atom is tetracoordinated by two 4,4′-bipydidine (4,4′-bipy) N atoms and two monodentate sulfonate O atoms of the 5-sulfoisophthalic acid (H(3) sip) ligands. Adjacent Ag atoms are bonded through four sulfonate O atoms, forming a dinuclear unit with an Ag⋯Ag separation of 3.384 (5) Å; they are further linked together by the 4,4′-bipy lignds into a chain. Classical intermolecular O—H⋯O and non-classical intramolecular C—H⋯O hydrogen bonds are also observed in the two-dimensional supramolecuar structure. |
format | Text |
id | pubmed-2983702 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29837022010-12-30 Poly[(μ(2)-4,4′-bipyridine)(μ(2)-3,5-dicarboxybenzenesulfonato)silver(I)] Lin, Dan Lian, Ping Xie, Yong-Rong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ag(C(8)H(5)O(7)S)(C(10)H(8)N(2))](n), the Ag atom is tetracoordinated by two 4,4′-bipydidine (4,4′-bipy) N atoms and two monodentate sulfonate O atoms of the 5-sulfoisophthalic acid (H(3) sip) ligands. Adjacent Ag atoms are bonded through four sulfonate O atoms, forming a dinuclear unit with an Ag⋯Ag separation of 3.384 (5) Å; they are further linked together by the 4,4′-bipy lignds into a chain. Classical intermolecular O—H⋯O and non-classical intramolecular C—H⋯O hydrogen bonds are also observed in the two-dimensional supramolecuar structure. International Union of Crystallography 2010-02-06 /pmc/articles/PMC2983702/ /pubmed/21580213 http://dx.doi.org/10.1107/S160053681000406X Text en © Lin et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Lin, Dan Lian, Ping Xie, Yong-Rong Poly[(μ(2)-4,4′-bipyridine)(μ(2)-3,5-dicarboxybenzenesulfonato)silver(I)] |
title | Poly[(μ(2)-4,4′-bipyridine)(μ(2)-3,5-dicarboxybenzenesulfonato)silver(I)] |
title_full | Poly[(μ(2)-4,4′-bipyridine)(μ(2)-3,5-dicarboxybenzenesulfonato)silver(I)] |
title_fullStr | Poly[(μ(2)-4,4′-bipyridine)(μ(2)-3,5-dicarboxybenzenesulfonato)silver(I)] |
title_full_unstemmed | Poly[(μ(2)-4,4′-bipyridine)(μ(2)-3,5-dicarboxybenzenesulfonato)silver(I)] |
title_short | Poly[(μ(2)-4,4′-bipyridine)(μ(2)-3,5-dicarboxybenzenesulfonato)silver(I)] |
title_sort | poly[(μ(2)-4,4′-bipyridine)(μ(2)-3,5-dicarboxybenzenesulfonato)silver(i)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983702/ https://www.ncbi.nlm.nih.gov/pubmed/21580213 http://dx.doi.org/10.1107/S160053681000406X |
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