Aluminium cyclo­hexa­phosphate

Single crystals of the title compound, Al(2)P(6)O(18), were obtained by solid-state reaction. The monoclinic structure is isotypic with its Cr(III), Ga(III) and Ru(III) analogues and is built up of six-membered phosphate ring anions, P(6)O(18) (6−), isolated from each other and further linked by iso...

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Detalles Bibliográficos
Autores principales: Oudahmane, Abdelghani, Mbarek, Aïcha, El-Ghozzi, Malika, Avignant, Daniel
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983707/
https://www.ncbi.nlm.nih.gov/pubmed/21580196
http://dx.doi.org/10.1107/S1600536810005374
Descripción
Sumario:Single crystals of the title compound, Al(2)P(6)O(18), were obtained by solid-state reaction. The monoclinic structure is isotypic with its Cr(III), Ga(III) and Ru(III) analogues and is built up of six-membered phosphate ring anions, P(6)O(18) (6−), isolated from each other and further linked by isolated AlO(6) octa­hedra by sharing corners. Each AlO(6) octa­hedron is linked to four P(6)O(18) (6−) rings. More accurately, two rings are linked through bidentate diphosphate groups attached in the cis-positions to the AlO(6) octa­hedron. The other two rings are linked to the two remaining corners, also in cis-positions of the AlO(6) octa­hedron.

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