Aluminium cyclo­hexa­phosphate

Single crystals of the title compound, Al(2)P(6)O(18), were obtained by solid-state reaction. The monoclinic structure is isotypic with its Cr(III), Ga(III) and Ru(III) analogues and is built up of six-membered phosphate ring anions, P(6)O(18) (6−), isolated from each other and further linked by iso...

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Autores principales: Oudahmane, Abdelghani, Mbarek, Aïcha, El-Ghozzi, Malika, Avignant, Daniel
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983707/
https://www.ncbi.nlm.nih.gov/pubmed/21580196
http://dx.doi.org/10.1107/S1600536810005374
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author Oudahmane, Abdelghani
Mbarek, Aïcha
El-Ghozzi, Malika
Avignant, Daniel
author_facet Oudahmane, Abdelghani
Mbarek, Aïcha
El-Ghozzi, Malika
Avignant, Daniel
author_sort Oudahmane, Abdelghani
collection PubMed
description Single crystals of the title compound, Al(2)P(6)O(18), were obtained by solid-state reaction. The monoclinic structure is isotypic with its Cr(III), Ga(III) and Ru(III) analogues and is built up of six-membered phosphate ring anions, P(6)O(18) (6−), isolated from each other and further linked by isolated AlO(6) octa­hedra by sharing corners. Each AlO(6) octa­hedron is linked to four P(6)O(18) (6−) rings. More accurately, two rings are linked through bidentate diphosphate groups attached in the cis-positions to the AlO(6) octa­hedron. The other two rings are linked to the two remaining corners, also in cis-positions of the AlO(6) octa­hedron.
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spelling pubmed-29837072010-12-30 Aluminium cyclo­hexa­phosphate Oudahmane, Abdelghani Mbarek, Aïcha El-Ghozzi, Malika Avignant, Daniel Acta Crystallogr Sect E Struct Rep Online Inorganic Papers Single crystals of the title compound, Al(2)P(6)O(18), were obtained by solid-state reaction. The monoclinic structure is isotypic with its Cr(III), Ga(III) and Ru(III) analogues and is built up of six-membered phosphate ring anions, P(6)O(18) (6−), isolated from each other and further linked by isolated AlO(6) octa­hedra by sharing corners. Each AlO(6) octa­hedron is linked to four P(6)O(18) (6−) rings. More accurately, two rings are linked through bidentate diphosphate groups attached in the cis-positions to the AlO(6) octa­hedron. The other two rings are linked to the two remaining corners, also in cis-positions of the AlO(6) octa­hedron. International Union of Crystallography 2010-02-13 /pmc/articles/PMC2983707/ /pubmed/21580196 http://dx.doi.org/10.1107/S1600536810005374 Text en © Oudahmane et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Oudahmane, Abdelghani
Mbarek, Aïcha
El-Ghozzi, Malika
Avignant, Daniel
Aluminium cyclo­hexa­phosphate
title Aluminium cyclo­hexa­phosphate
title_full Aluminium cyclo­hexa­phosphate
title_fullStr Aluminium cyclo­hexa­phosphate
title_full_unstemmed Aluminium cyclo­hexa­phosphate
title_short Aluminium cyclo­hexa­phosphate
title_sort aluminium cyclo­hexa­phosphate
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983707/
https://www.ncbi.nlm.nih.gov/pubmed/21580196
http://dx.doi.org/10.1107/S1600536810005374
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AT mbarekaicha aluminiumcyclohexaphosphate
AT elghozzimalika aluminiumcyclohexaphosphate
AT avignantdaniel aluminiumcyclohexaphosphate

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