Tetra­kis(μ-3,4-dimethoxy­phenyl­acetato)bis­[(3,4-dimethoxy­phenyl­acetato)(1,10-phenanthroline)dysprosium(III)]

The title centrosymmetric dinuclear dysprosium(III) complex, [Dy(2)(C(10)H(11)O(4))(6)(C(12)H(8)N(2))(2)] or [Dy(L)(3)phen](2), is comprised of six 3,4-dimethoxy­phenylacetate (L) anions, two 1,10-phenanthroline (phen) mol­ecules and two Dy(III) ions. The Dy(III) atom is nine-coordinated by seven O...

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Detalles Bibliográficos
Autores principales: Liu, Jian-Feng, Xu, Xue-Dan, Li, Hua-Qiong, Zhao, Guo-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983715/
https://www.ncbi.nlm.nih.gov/pubmed/21580236
http://dx.doi.org/10.1107/S1600536810005143
Descripción
Sumario:The title centrosymmetric dinuclear dysprosium(III) complex, [Dy(2)(C(10)H(11)O(4))(6)(C(12)H(8)N(2))(2)] or [Dy(L)(3)phen](2), is comprised of six 3,4-dimethoxy­phenylacetate (L) anions, two 1,10-phenanthroline (phen) mol­ecules and two Dy(III) ions. The Dy(III) atom is nine-coordinated by seven O atoms from five L ligands and two N atoms from the phen mol­ecules. The L ligands are coordinated to the Dy(III) ion in three coordination modes: chelating, bridging and bridging-tridentate. C—H⋯O hydrogen bonding interactions consolidate the crystal packing.

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