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Tetrakis(μ-3,4-dimethoxyphenylacetato)bis[(3,4-dimethoxyphenylacetato)(1,10-phenanthroline)dysprosium(III)]
The title centrosymmetric dinuclear dysprosium(III) complex, [Dy(2)(C(10)H(11)O(4))(6)(C(12)H(8)N(2))(2)] or [Dy(L)(3)phen](2), is comprised of six 3,4-dimethoxyphenylacetate (L) anions, two 1,10-phenanthroline (phen) molecules and two Dy(III) ions. The Dy(III) atom is nine-coordinated by seven O...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983715/ https://www.ncbi.nlm.nih.gov/pubmed/21580236 http://dx.doi.org/10.1107/S1600536810005143 |
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author | Liu, Jian-Feng Xu, Xue-Dan Li, Hua-Qiong Zhao, Guo-Liang |
author_facet | Liu, Jian-Feng Xu, Xue-Dan Li, Hua-Qiong Zhao, Guo-Liang |
author_sort | Liu, Jian-Feng |
collection | PubMed |
description | The title centrosymmetric dinuclear dysprosium(III) complex, [Dy(2)(C(10)H(11)O(4))(6)(C(12)H(8)N(2))(2)] or [Dy(L)(3)phen](2), is comprised of six 3,4-dimethoxyphenylacetate (L) anions, two 1,10-phenanthroline (phen) molecules and two Dy(III) ions. The Dy(III) atom is nine-coordinated by seven O atoms from five L ligands and two N atoms from the phen molecules. The L ligands are coordinated to the Dy(III) ion in three coordination modes: chelating, bridging and bridging-tridentate. C—H⋯O hydrogen bonding interactions consolidate the crystal packing. |
format | Text |
id | pubmed-2983715 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29837152010-12-30 Tetrakis(μ-3,4-dimethoxyphenylacetato)bis[(3,4-dimethoxyphenylacetato)(1,10-phenanthroline)dysprosium(III)] Liu, Jian-Feng Xu, Xue-Dan Li, Hua-Qiong Zhao, Guo-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title centrosymmetric dinuclear dysprosium(III) complex, [Dy(2)(C(10)H(11)O(4))(6)(C(12)H(8)N(2))(2)] or [Dy(L)(3)phen](2), is comprised of six 3,4-dimethoxyphenylacetate (L) anions, two 1,10-phenanthroline (phen) molecules and two Dy(III) ions. The Dy(III) atom is nine-coordinated by seven O atoms from five L ligands and two N atoms from the phen molecules. The L ligands are coordinated to the Dy(III) ion in three coordination modes: chelating, bridging and bridging-tridentate. C—H⋯O hydrogen bonding interactions consolidate the crystal packing. International Union of Crystallography 2010-02-13 /pmc/articles/PMC2983715/ /pubmed/21580236 http://dx.doi.org/10.1107/S1600536810005143 Text en © Liu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Liu, Jian-Feng Xu, Xue-Dan Li, Hua-Qiong Zhao, Guo-Liang Tetrakis(μ-3,4-dimethoxyphenylacetato)bis[(3,4-dimethoxyphenylacetato)(1,10-phenanthroline)dysprosium(III)] |
title | Tetrakis(μ-3,4-dimethoxyphenylacetato)bis[(3,4-dimethoxyphenylacetato)(1,10-phenanthroline)dysprosium(III)] |
title_full | Tetrakis(μ-3,4-dimethoxyphenylacetato)bis[(3,4-dimethoxyphenylacetato)(1,10-phenanthroline)dysprosium(III)] |
title_fullStr | Tetrakis(μ-3,4-dimethoxyphenylacetato)bis[(3,4-dimethoxyphenylacetato)(1,10-phenanthroline)dysprosium(III)] |
title_full_unstemmed | Tetrakis(μ-3,4-dimethoxyphenylacetato)bis[(3,4-dimethoxyphenylacetato)(1,10-phenanthroline)dysprosium(III)] |
title_short | Tetrakis(μ-3,4-dimethoxyphenylacetato)bis[(3,4-dimethoxyphenylacetato)(1,10-phenanthroline)dysprosium(III)] |
title_sort | tetrakis(μ-3,4-dimethoxyphenylacetato)bis[(3,4-dimethoxyphenylacetato)(1,10-phenanthroline)dysprosium(iii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983715/ https://www.ncbi.nlm.nih.gov/pubmed/21580236 http://dx.doi.org/10.1107/S1600536810005143 |
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