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2,2′-(2,6-Pyridinediyl)diquinoline
The title molecule, C(23)H(15)N(3), is a terpyridine derivative resulting from the Friedländer annulation between 2,6-diacetylpyridine and N,N′-bis(2-aminobenzyl)ethylenediamine. The asymmetric unit contains one half-molecule, the complete molecule being generated by a mirror plane (one N...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983720/ https://www.ncbi.nlm.nih.gov/pubmed/21580414 http://dx.doi.org/10.1107/S1600536810006033 |
Sumario: | The title molecule, C(23)H(15)N(3), is a terpyridine derivative resulting from the Friedländer annulation between 2,6-diacetylpyridine and N,N′-bis(2-aminobenzyl)ethylenediamine. The asymmetric unit contains one half-molecule, the complete molecule being generated by a mirror plane (one N atom and one C atom lie on the plane). The molecule, although aromatic, is deformed from planarity as a result of crystal packing forces: molecules are stacked along the short c axis, with a short separation of 3.605 (1) Å between the mean planes. The bent molecular shape is reflected in the dihedral angle of 16.10 (5)° between the essentially planar quinoline groups. In addition to π⋯π interactions, the crystal structure features weak inter-stack C—H⋯N contacts involving atoms of the central pyridine rings which lie in a common crystallographic m plane. |
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