1,2-Bis(4-ethynylphen­yl)disulfane

In the title compound, C(16)H(10)S(2), the S atoms are almost coplanar with the benzene rings to which they are bonded [deviations of 0.092 (1) and 0.022 (1) Å from their respective ring planes]. The benzene rings enclose a dihedral angle of 79.17 (3)°. An intra­molecular C—H⋯S hydrogen bond results...

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Detalles Bibliográficos
Autores principales: Xiao, Qi, Liu, Rui, Li, Yu-Hao, Chen, Hong-Bin, Zhu, Hong-Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983721/
https://www.ncbi.nlm.nih.gov/pubmed/21580365
http://dx.doi.org/10.1107/S1600536810004721
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author Xiao, Qi
Liu, Rui
Li, Yu-Hao
Chen, Hong-Bin
Zhu, Hong-Jun
author_facet Xiao, Qi
Liu, Rui
Li, Yu-Hao
Chen, Hong-Bin
Zhu, Hong-Jun
author_sort Xiao, Qi
collection PubMed
description In the title compound, C(16)H(10)S(2), the S atoms are almost coplanar with the benzene rings to which they are bonded [deviations of 0.092 (1) and 0.022 (1) Å from their respective ring planes]. The benzene rings enclose a dihedral angle of 79.17 (3)°. An intra­molecular C—H⋯S hydrogen bond results in the formation of a five-membered ring. In the crystal structure, mol­ecules are stacked parallel to the a axis direction. π–π inter­actions between benzene rings are present, with a face-to-face stacking distance of 3.622 (10) Å.
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spelling pubmed-29837212010-12-30 1,2-Bis(4-ethynylphen­yl)disulfane Xiao, Qi Liu, Rui Li, Yu-Hao Chen, Hong-Bin Zhu, Hong-Jun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(10)S(2), the S atoms are almost coplanar with the benzene rings to which they are bonded [deviations of 0.092 (1) and 0.022 (1) Å from their respective ring planes]. The benzene rings enclose a dihedral angle of 79.17 (3)°. An intra­molecular C—H⋯S hydrogen bond results in the formation of a five-membered ring. In the crystal structure, mol­ecules are stacked parallel to the a axis direction. π–π inter­actions between benzene rings are present, with a face-to-face stacking distance of 3.622 (10) Å. International Union of Crystallography 2010-02-13 /pmc/articles/PMC2983721/ /pubmed/21580365 http://dx.doi.org/10.1107/S1600536810004721 Text en © Xiao et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Xiao, Qi
Liu, Rui
Li, Yu-Hao
Chen, Hong-Bin
Zhu, Hong-Jun
1,2-Bis(4-ethynylphen­yl)disulfane
title 1,2-Bis(4-ethynylphen­yl)disulfane
title_full 1,2-Bis(4-ethynylphen­yl)disulfane
title_fullStr 1,2-Bis(4-ethynylphen­yl)disulfane
title_full_unstemmed 1,2-Bis(4-ethynylphen­yl)disulfane
title_short 1,2-Bis(4-ethynylphen­yl)disulfane
title_sort 1,2-bis(4-ethynylphen­yl)disulfane
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983721/
https://www.ncbi.nlm.nih.gov/pubmed/21580365
http://dx.doi.org/10.1107/S1600536810004721
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AT liyuhao 12bis4ethynylphenyldisulfane
AT chenhongbin 12bis4ethynylphenyldisulfane
AT zhuhongjun 12bis4ethynylphenyldisulfane

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