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(E)-1,2-Bis(1-propyl-5,6-dimethyl-1H-benzimidazol-2-yl)ethene

In the title compound, C(26)H(32)N(4), the essentially planar (r.m.s. deviations of 0.0053 and 0.0242 Å) benzimidazole fragments are trans with respect to a central ethene fragment, and are canted in opposite directions by 2.78 (6) and 5.87 (6)° with respect to the ethene plane, giving the mol­ecule...

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Detalles Bibliográficos
Autores principales: Stibrany, Robert T., Potenza, Joseph A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983724/
https://www.ncbi.nlm.nih.gov/pubmed/21580350
http://dx.doi.org/10.1107/S1600536810003405
Descripción
Sumario:In the title compound, C(26)H(32)N(4), the essentially planar (r.m.s. deviations of 0.0053 and 0.0242 Å) benzimidazole fragments are trans with respect to a central ethene fragment, and are canted in opposite directions by 2.78 (6) and 5.87 (6)° with respect to the ethene plane, giving the mol­ecule a propeller conformation. The terminal ethyl fragments of the pendant n-propyl groups protrude to either side of the benzimidazole planes. Overall, the mol­ecule exhibits a pseudo-center of symmetry at the mid-point of the ethene fragment. Both π–π stacking and typical C—H⋯π inter­actions are notably absent, as are inter­molecular hydrogen bonds. When viewed along the a axis, the structure appears as criss-crossed layers of mol­ecules with the planar fragments separated along the c-cell direction by the protruding ethyl groups.