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(E)-1,2-Bis(1-propyl-5,6-dimethyl-1H-benzimidazol-2-yl)ethene

In the title compound, C(26)H(32)N(4), the essentially planar (r.m.s. deviations of 0.0053 and 0.0242 Å) benzimidazole fragments are trans with respect to a central ethene fragment, and are canted in opposite directions by 2.78 (6) and 5.87 (6)° with respect to the ethene plane, giving the mol­ecule...

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Detalles Bibliográficos
Autores principales: Stibrany, Robert T., Potenza, Joseph A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983724/
https://www.ncbi.nlm.nih.gov/pubmed/21580350
http://dx.doi.org/10.1107/S1600536810003405
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author Stibrany, Robert T.
Potenza, Joseph A.
author_facet Stibrany, Robert T.
Potenza, Joseph A.
author_sort Stibrany, Robert T.
collection PubMed
description In the title compound, C(26)H(32)N(4), the essentially planar (r.m.s. deviations of 0.0053 and 0.0242 Å) benzimidazole fragments are trans with respect to a central ethene fragment, and are canted in opposite directions by 2.78 (6) and 5.87 (6)° with respect to the ethene plane, giving the mol­ecule a propeller conformation. The terminal ethyl fragments of the pendant n-propyl groups protrude to either side of the benzimidazole planes. Overall, the mol­ecule exhibits a pseudo-center of symmetry at the mid-point of the ethene fragment. Both π–π stacking and typical C—H⋯π inter­actions are notably absent, as are inter­molecular hydrogen bonds. When viewed along the a axis, the structure appears as criss-crossed layers of mol­ecules with the planar fragments separated along the c-cell direction by the protruding ethyl groups.
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spelling pubmed-29837242010-12-30 (E)-1,2-Bis(1-propyl-5,6-dimethyl-1H-benzimidazol-2-yl)ethene Stibrany, Robert T. Potenza, Joseph A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(26)H(32)N(4), the essentially planar (r.m.s. deviations of 0.0053 and 0.0242 Å) benzimidazole fragments are trans with respect to a central ethene fragment, and are canted in opposite directions by 2.78 (6) and 5.87 (6)° with respect to the ethene plane, giving the mol­ecule a propeller conformation. The terminal ethyl fragments of the pendant n-propyl groups protrude to either side of the benzimidazole planes. Overall, the mol­ecule exhibits a pseudo-center of symmetry at the mid-point of the ethene fragment. Both π–π stacking and typical C—H⋯π inter­actions are notably absent, as are inter­molecular hydrogen bonds. When viewed along the a axis, the structure appears as criss-crossed layers of mol­ecules with the planar fragments separated along the c-cell direction by the protruding ethyl groups. International Union of Crystallography 2010-02-10 /pmc/articles/PMC2983724/ /pubmed/21580350 http://dx.doi.org/10.1107/S1600536810003405 Text en © Stibrany and Potenza 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Stibrany, Robert T.
Potenza, Joseph A.
(E)-1,2-Bis(1-propyl-5,6-dimethyl-1H-benzimidazol-2-yl)ethene
title (E)-1,2-Bis(1-propyl-5,6-dimethyl-1H-benzimidazol-2-yl)ethene
title_full (E)-1,2-Bis(1-propyl-5,6-dimethyl-1H-benzimidazol-2-yl)ethene
title_fullStr (E)-1,2-Bis(1-propyl-5,6-dimethyl-1H-benzimidazol-2-yl)ethene
title_full_unstemmed (E)-1,2-Bis(1-propyl-5,6-dimethyl-1H-benzimidazol-2-yl)ethene
title_short (E)-1,2-Bis(1-propyl-5,6-dimethyl-1H-benzimidazol-2-yl)ethene
title_sort (e)-1,2-bis(1-propyl-5,6-dimethyl-1h-benzimidazol-2-yl)ethene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983724/
https://www.ncbi.nlm.nih.gov/pubmed/21580350
http://dx.doi.org/10.1107/S1600536810003405
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