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(E)-1,2-Bis(1-propyl-5,6-dimethyl-1H-benzimidazol-2-yl)ethene
In the title compound, C(26)H(32)N(4), the essentially planar (r.m.s. deviations of 0.0053 and 0.0242 Å) benzimidazole fragments are trans with respect to a central ethene fragment, and are canted in opposite directions by 2.78 (6) and 5.87 (6)° with respect to the ethene plane, giving the molecule...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983724/ https://www.ncbi.nlm.nih.gov/pubmed/21580350 http://dx.doi.org/10.1107/S1600536810003405 |
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author | Stibrany, Robert T. Potenza, Joseph A. |
author_facet | Stibrany, Robert T. Potenza, Joseph A. |
author_sort | Stibrany, Robert T. |
collection | PubMed |
description | In the title compound, C(26)H(32)N(4), the essentially planar (r.m.s. deviations of 0.0053 and 0.0242 Å) benzimidazole fragments are trans with respect to a central ethene fragment, and are canted in opposite directions by 2.78 (6) and 5.87 (6)° with respect to the ethene plane, giving the molecule a propeller conformation. The terminal ethyl fragments of the pendant n-propyl groups protrude to either side of the benzimidazole planes. Overall, the molecule exhibits a pseudo-center of symmetry at the mid-point of the ethene fragment. Both π–π stacking and typical C—H⋯π interactions are notably absent, as are intermolecular hydrogen bonds. When viewed along the a axis, the structure appears as criss-crossed layers of molecules with the planar fragments separated along the c-cell direction by the protruding ethyl groups. |
format | Text |
id | pubmed-2983724 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29837242010-12-30 (E)-1,2-Bis(1-propyl-5,6-dimethyl-1H-benzimidazol-2-yl)ethene Stibrany, Robert T. Potenza, Joseph A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(26)H(32)N(4), the essentially planar (r.m.s. deviations of 0.0053 and 0.0242 Å) benzimidazole fragments are trans with respect to a central ethene fragment, and are canted in opposite directions by 2.78 (6) and 5.87 (6)° with respect to the ethene plane, giving the molecule a propeller conformation. The terminal ethyl fragments of the pendant n-propyl groups protrude to either side of the benzimidazole planes. Overall, the molecule exhibits a pseudo-center of symmetry at the mid-point of the ethene fragment. Both π–π stacking and typical C—H⋯π interactions are notably absent, as are intermolecular hydrogen bonds. When viewed along the a axis, the structure appears as criss-crossed layers of molecules with the planar fragments separated along the c-cell direction by the protruding ethyl groups. International Union of Crystallography 2010-02-10 /pmc/articles/PMC2983724/ /pubmed/21580350 http://dx.doi.org/10.1107/S1600536810003405 Text en © Stibrany and Potenza 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Stibrany, Robert T. Potenza, Joseph A. (E)-1,2-Bis(1-propyl-5,6-dimethyl-1H-benzimidazol-2-yl)ethene |
title | (E)-1,2-Bis(1-propyl-5,6-dimethyl-1H-benzimidazol-2-yl)ethene |
title_full | (E)-1,2-Bis(1-propyl-5,6-dimethyl-1H-benzimidazol-2-yl)ethene |
title_fullStr | (E)-1,2-Bis(1-propyl-5,6-dimethyl-1H-benzimidazol-2-yl)ethene |
title_full_unstemmed | (E)-1,2-Bis(1-propyl-5,6-dimethyl-1H-benzimidazol-2-yl)ethene |
title_short | (E)-1,2-Bis(1-propyl-5,6-dimethyl-1H-benzimidazol-2-yl)ethene |
title_sort | (e)-1,2-bis(1-propyl-5,6-dimethyl-1h-benzimidazol-2-yl)ethene |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983724/ https://www.ncbi.nlm.nih.gov/pubmed/21580350 http://dx.doi.org/10.1107/S1600536810003405 |
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