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Diaqua­bis(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))nickel(II) N,N-dimethyl­formamide disolvate

In the title complex, [Ni(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·2C(3)H(7)NO, the Ni(II) atom is six-coordinated by two N,O-bidentate 5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ate ligands and two water mol­ecules in a distorted octa­hedral environment. The methyl C and H atoms of the two ligands are diso...

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Detalles Bibliográficos
Autores principales: Li, Shi-Jie, Yan, Jian-Bin, Song, Wen-Dong, Wang, Hao, Miao, Dong-Liang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983735/
https://www.ncbi.nlm.nih.gov/pubmed/21580226
http://dx.doi.org/10.1107/S1600536810004691
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author Li, Shi-Jie
Yan, Jian-Bin
Song, Wen-Dong
Wang, Hao
Miao, Dong-Liang
author_facet Li, Shi-Jie
Yan, Jian-Bin
Song, Wen-Dong
Wang, Hao
Miao, Dong-Liang
author_sort Li, Shi-Jie
collection PubMed
description In the title complex, [Ni(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·2C(3)H(7)NO, the Ni(II) atom is six-coordinated by two N,O-bidentate 5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ate ligands and two water mol­ecules in a distorted octa­hedral environment. The methyl C and H atoms of the two ligands are disordered over two sets of sites in 0.74 (2):0.26 (2) and 0.57 (8):0.43 (8) ratios. A supra­molecular network is stabilized by intra- and inter­molecular N—H⋯O and O—H⋯O hydrogen bonds involving the ligands, coordinated water mol­ecules and dimethyl­formamide solvent mol­ecules.
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spelling pubmed-29837352010-12-30 Diaqua­bis(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))nickel(II) N,N-dimethyl­formamide disolvate Li, Shi-Jie Yan, Jian-Bin Song, Wen-Dong Wang, Hao Miao, Dong-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·2C(3)H(7)NO, the Ni(II) atom is six-coordinated by two N,O-bidentate 5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ate ligands and two water mol­ecules in a distorted octa­hedral environment. The methyl C and H atoms of the two ligands are disordered over two sets of sites in 0.74 (2):0.26 (2) and 0.57 (8):0.43 (8) ratios. A supra­molecular network is stabilized by intra- and inter­molecular N—H⋯O and O—H⋯O hydrogen bonds involving the ligands, coordinated water mol­ecules and dimethyl­formamide solvent mol­ecules. International Union of Crystallography 2010-02-13 /pmc/articles/PMC2983735/ /pubmed/21580226 http://dx.doi.org/10.1107/S1600536810004691 Text en © Li et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Shi-Jie
Yan, Jian-Bin
Song, Wen-Dong
Wang, Hao
Miao, Dong-Liang
Diaqua­bis(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))nickel(II) N,N-dimethyl­formamide disolvate
title Diaqua­bis(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))nickel(II) N,N-dimethyl­formamide disolvate
title_full Diaqua­bis(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))nickel(II) N,N-dimethyl­formamide disolvate
title_fullStr Diaqua­bis(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))nickel(II) N,N-dimethyl­formamide disolvate
title_full_unstemmed Diaqua­bis(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))nickel(II) N,N-dimethyl­formamide disolvate
title_short Diaqua­bis(5-carb­oxy-2-propyl-1H-imidazole-4-carboxyl­ato-κ(2) N (3),O (4))nickel(II) N,N-dimethyl­formamide disolvate
title_sort diaqua­bis(5-carb­oxy-2-propyl-1h-imidazole-4-carboxyl­ato-κ(2) n (3),o (4))nickel(ii) n,n-dimethyl­formamide disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983735/
https://www.ncbi.nlm.nih.gov/pubmed/21580226
http://dx.doi.org/10.1107/S1600536810004691
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