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Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(2) N (3),O (4))nickel(II) N,N-dimethylformamide disolvate
In the title complex, [Ni(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·2C(3)H(7)NO, the Ni(II) atom is six-coordinated by two N,O-bidentate 5-carboxy-2-propyl-1H-imidazole-4-carboxylate ligands and two water molecules in a distorted octahedral environment. The methyl C and H atoms of the two ligands are diso...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983735/ https://www.ncbi.nlm.nih.gov/pubmed/21580226 http://dx.doi.org/10.1107/S1600536810004691 |
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author | Li, Shi-Jie Yan, Jian-Bin Song, Wen-Dong Wang, Hao Miao, Dong-Liang |
author_facet | Li, Shi-Jie Yan, Jian-Bin Song, Wen-Dong Wang, Hao Miao, Dong-Liang |
author_sort | Li, Shi-Jie |
collection | PubMed |
description | In the title complex, [Ni(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·2C(3)H(7)NO, the Ni(II) atom is six-coordinated by two N,O-bidentate 5-carboxy-2-propyl-1H-imidazole-4-carboxylate ligands and two water molecules in a distorted octahedral environment. The methyl C and H atoms of the two ligands are disordered over two sets of sites in 0.74 (2):0.26 (2) and 0.57 (8):0.43 (8) ratios. A supramolecular network is stabilized by intra- and intermolecular N—H⋯O and O—H⋯O hydrogen bonds involving the ligands, coordinated water molecules and dimethylformamide solvent molecules. |
format | Text |
id | pubmed-2983735 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29837352010-12-30 Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(2) N (3),O (4))nickel(II) N,N-dimethylformamide disolvate Li, Shi-Jie Yan, Jian-Bin Song, Wen-Dong Wang, Hao Miao, Dong-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ni(C(8)H(9)N(2)O(4))(2)(H(2)O)(2)]·2C(3)H(7)NO, the Ni(II) atom is six-coordinated by two N,O-bidentate 5-carboxy-2-propyl-1H-imidazole-4-carboxylate ligands and two water molecules in a distorted octahedral environment. The methyl C and H atoms of the two ligands are disordered over two sets of sites in 0.74 (2):0.26 (2) and 0.57 (8):0.43 (8) ratios. A supramolecular network is stabilized by intra- and intermolecular N—H⋯O and O—H⋯O hydrogen bonds involving the ligands, coordinated water molecules and dimethylformamide solvent molecules. International Union of Crystallography 2010-02-13 /pmc/articles/PMC2983735/ /pubmed/21580226 http://dx.doi.org/10.1107/S1600536810004691 Text en © Li et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Shi-Jie Yan, Jian-Bin Song, Wen-Dong Wang, Hao Miao, Dong-Liang Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(2) N (3),O (4))nickel(II) N,N-dimethylformamide disolvate |
title | Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))nickel(II) N,N-dimethylformamide disolvate |
title_full | Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))nickel(II) N,N-dimethylformamide disolvate |
title_fullStr | Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))nickel(II) N,N-dimethylformamide disolvate |
title_full_unstemmed | Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))nickel(II) N,N-dimethylformamide disolvate |
title_short | Diaquabis(5-carboxy-2-propyl-1H-imidazole-4-carboxylato-κ(2)
N
(3),O
(4))nickel(II) N,N-dimethylformamide disolvate |
title_sort | diaquabis(5-carboxy-2-propyl-1h-imidazole-4-carboxylato-κ(2)
n
(3),o
(4))nickel(ii) n,n-dimethylformamide disolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983735/ https://www.ncbi.nlm.nih.gov/pubmed/21580226 http://dx.doi.org/10.1107/S1600536810004691 |
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