Hexakis(N,N-dimethyl­formamide-κO)cobalt(II) bis­(perchlorate)

The asymmetric unit of the title complex, [Co(DMF)(6)](ClO(4))(2) (DMF = N,N-dimethyl­formamide, C(3)H(7)NO), consists of two half complex cations with the Co(2+) metal ions located on centers of inversion and two perchlorate anions. In the crystal packing, each Co(2+) ion is coordinated by six mol­...

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Detalles Bibliográficos
Autores principales: Eissmann, Frank, Böhle, Tony, Mertens, Florian O. R. L., Weber, Edwin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983736/
https://www.ncbi.nlm.nih.gov/pubmed/21580225
http://dx.doi.org/10.1107/S160053681000454X
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author Eissmann, Frank
Böhle, Tony
Mertens, Florian O. R. L.
Weber, Edwin
author_facet Eissmann, Frank
Böhle, Tony
Mertens, Florian O. R. L.
Weber, Edwin
author_sort Eissmann, Frank
collection PubMed
description The asymmetric unit of the title complex, [Co(DMF)(6)](ClO(4))(2) (DMF = N,N-dimethyl­formamide, C(3)H(7)NO), consists of two half complex cations with the Co(2+) metal ions located on centers of inversion and two perchlorate anions. In the crystal packing, each Co(2+) ion is coordinated by six mol­ecules of DMF in a slightly distorted octa­hedral geometry. The crystal structure is mainly stabilized by coordinative, ionic and C—H⋯O hydrogen-bonding inter­actions.
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spelling pubmed-29837362010-12-30 Hexakis(N,N-dimethyl­formamide-κO)cobalt(II) bis­(perchlorate) Eissmann, Frank Böhle, Tony Mertens, Florian O. R. L. Weber, Edwin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, [Co(DMF)(6)](ClO(4))(2) (DMF = N,N-dimethyl­formamide, C(3)H(7)NO), consists of two half complex cations with the Co(2+) metal ions located on centers of inversion and two perchlorate anions. In the crystal packing, each Co(2+) ion is coordinated by six mol­ecules of DMF in a slightly distorted octa­hedral geometry. The crystal structure is mainly stabilized by coordinative, ionic and C—H⋯O hydrogen-bonding inter­actions. International Union of Crystallography 2010-02-10 /pmc/articles/PMC2983736/ /pubmed/21580225 http://dx.doi.org/10.1107/S160053681000454X Text en © Eissmann et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Eissmann, Frank
Böhle, Tony
Mertens, Florian O. R. L.
Weber, Edwin
Hexakis(N,N-dimethyl­formamide-κO)cobalt(II) bis­(perchlorate)
title Hexakis(N,N-dimethyl­formamide-κO)cobalt(II) bis­(perchlorate)
title_full Hexakis(N,N-dimethyl­formamide-κO)cobalt(II) bis­(perchlorate)
title_fullStr Hexakis(N,N-dimethyl­formamide-κO)cobalt(II) bis­(perchlorate)
title_full_unstemmed Hexakis(N,N-dimethyl­formamide-κO)cobalt(II) bis­(perchlorate)
title_short Hexakis(N,N-dimethyl­formamide-κO)cobalt(II) bis­(perchlorate)
title_sort hexakis(n,n-dimethyl­formamide-κo)cobalt(ii) bis­(perchlorate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983736/
https://www.ncbi.nlm.nih.gov/pubmed/21580225
http://dx.doi.org/10.1107/S160053681000454X
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