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Bis(tetraphenylphosphonium) bis[N-(2,5-dichlorophenylsulfonyl)dithiocarbimato(2−)-κ(2) S,S′]platinate(II)
In the title salt, (C(24)H(20)P)(2)[Pt(C(7)H(3)Cl(2)NO(2)S(3))(2)], the Pt(II) ion (site symmetry [Image: see text]) is coordinated by two S,S′-bidentate N-(2,5-dichlorophenylsulfonyl)dithiocarbimate ligands, resulting in a slightly distorted PtS(4) square-planar geometry. In the crystal, a C—H⋯...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983738/ https://www.ncbi.nlm.nih.gov/pubmed/21580206 http://dx.doi.org/10.1107/S1600536810003272 |
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| author | Guilardi, S. Flauzino Neto, Wilson P. Vieira, Lucas C. C. Amin, Raquel S. Oliveira, Marcelo R. L. |
| author_facet | Guilardi, S. Flauzino Neto, Wilson P. Vieira, Lucas C. C. Amin, Raquel S. Oliveira, Marcelo R. L. |
| author_sort | Guilardi, S. |
| collection | PubMed |
| description | In the title salt, (C(24)H(20)P)(2)[Pt(C(7)H(3)Cl(2)NO(2)S(3))(2)], the Pt(II) ion (site symmetry [Image: see text]) is coordinated by two S,S′-bidentate N-(2,5-dichlorophenylsulfonyl)dithiocarbimate ligands, resulting in a slightly distorted PtS(4) square-planar geometry. In the crystal, a C—H⋯O interaction is observed, as well as electrostatic attraction between the oppositely charged ions. |
| format | Text |
| id | pubmed-2983738 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29837382010-12-30 Bis(tetraphenylphosphonium) bis[N-(2,5-dichlorophenylsulfonyl)dithiocarbimato(2−)-κ(2) S,S′]platinate(II) Guilardi, S. Flauzino Neto, Wilson P. Vieira, Lucas C. C. Amin, Raquel S. Oliveira, Marcelo R. L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, (C(24)H(20)P)(2)[Pt(C(7)H(3)Cl(2)NO(2)S(3))(2)], the Pt(II) ion (site symmetry [Image: see text]) is coordinated by two S,S′-bidentate N-(2,5-dichlorophenylsulfonyl)dithiocarbimate ligands, resulting in a slightly distorted PtS(4) square-planar geometry. In the crystal, a C—H⋯O interaction is observed, as well as electrostatic attraction between the oppositely charged ions. International Union of Crystallography 2010-02-03 /pmc/articles/PMC2983738/ /pubmed/21580206 http://dx.doi.org/10.1107/S1600536810003272 Text en © Guilardi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Guilardi, S. Flauzino Neto, Wilson P. Vieira, Lucas C. C. Amin, Raquel S. Oliveira, Marcelo R. L. Bis(tetraphenylphosphonium) bis[N-(2,5-dichlorophenylsulfonyl)dithiocarbimato(2−)-κ(2) S,S′]platinate(II) |
| title | Bis(tetraphenylphosphonium) bis[N-(2,5-dichlorophenylsulfonyl)dithiocarbimato(2−)-κ(2)
S,S′]platinate(II) |
| title_full | Bis(tetraphenylphosphonium) bis[N-(2,5-dichlorophenylsulfonyl)dithiocarbimato(2−)-κ(2)
S,S′]platinate(II) |
| title_fullStr | Bis(tetraphenylphosphonium) bis[N-(2,5-dichlorophenylsulfonyl)dithiocarbimato(2−)-κ(2)
S,S′]platinate(II) |
| title_full_unstemmed | Bis(tetraphenylphosphonium) bis[N-(2,5-dichlorophenylsulfonyl)dithiocarbimato(2−)-κ(2)
S,S′]platinate(II) |
| title_short | Bis(tetraphenylphosphonium) bis[N-(2,5-dichlorophenylsulfonyl)dithiocarbimato(2−)-κ(2)
S,S′]platinate(II) |
| title_sort | bis(tetraphenylphosphonium) bis[n-(2,5-dichlorophenylsulfonyl)dithiocarbimato(2−)-κ(2)
s,s′]platinate(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983738/ https://www.ncbi.nlm.nih.gov/pubmed/21580206 http://dx.doi.org/10.1107/S1600536810003272 |
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