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2-Amino-5-chloropyridinium 4-hydroxybenzoate
In the title salt, C(5)H(6)ClN(2) (+)·C(7)H(5)O(3) (−), the carboxylate mean plane of the 4-hydroxybenzoate anion is twisted by 7.16 (9)° from the attached ring. In the crystal structure, the cations and anions are linked via O—H⋯O and N—H⋯O hydrogen bonds, as well as C—H⋯O contacts, forming a thr...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983740/ https://www.ncbi.nlm.nih.gov/pubmed/21580326 http://dx.doi.org/10.1107/S1600536810004265 |
Sumario: | In the title salt, C(5)H(6)ClN(2) (+)·C(7)H(5)O(3) (−), the carboxylate mean plane of the 4-hydroxybenzoate anion is twisted by 7.16 (9)° from the attached ring. In the crystal structure, the cations and anions are linked via O—H⋯O and N—H⋯O hydrogen bonds, as well as C—H⋯O contacts, forming a three-dimensional network. In addition, weak π–π interactions involving the benzene and pyridinium rings, with centroid-to-centroid distances of 3.8941 (9) Å, are observed. |
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