fac-(2-Amido­ethyl-κ(2) C (1),O)aqua­tri­chlorido­tin(IV) 1,4,7,10,13,16-hexa­oxacyclo­octa­decane (2/1)

The asymmetric unit of the title compound, [Sn(C(3)H(6)NO)Cl(3)(H(2)O)](2)·C(12)H(24)O(6), comprises a six-coordinate tin complex and a 18-crown-6 mol­ecule, the latter disposed about a centre of inversion. The tin atom is coordinated by three Cl atoms, that define a facial arrangement, a chelating...

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Detalles Bibliográficos
Autores principales: Wardell, Solange M. S. V., Harrison, William T. A., Tiekink, Edward R. T., de Lima, Geraldo M., Wardell, James L.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983741/
https://www.ncbi.nlm.nih.gov/pubmed/21580253
http://dx.doi.org/10.1107/S1600536810005908
Descripción
Sumario:The asymmetric unit of the title compound, [Sn(C(3)H(6)NO)Cl(3)(H(2)O)](2)·C(12)H(24)O(6), comprises a six-coordinate tin complex and a 18-crown-6 mol­ecule, the latter disposed about a centre of inversion. The tin atom is coordinated by three Cl atoms, that define a facial arrangement, a chelating C-,O- ligand, and a water mol­ecule. The resulting CCl(3)O(2) donor set defines a distorted octa­hedral geometry. The tin-bound aqua ligand forms O—H⋯O hydrogen bonds to the centrosymmetric 18-crown-6 mol­ecule, resulting in a tri-mol­ecular aggregate. These assemble into a supra­molecular chain along the a axis being connected by N—H⋯O hydrogen bonds.

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