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fac-(2-Amidoethyl-κ(2) C (1),O)aquatrichloridotin(IV) 1,4,7,10,13,16-hexaoxacyclooctadecane (2/1)
The asymmetric unit of the title compound, [Sn(C(3)H(6)NO)Cl(3)(H(2)O)](2)·C(12)H(24)O(6), comprises a six-coordinate tin complex and a 18-crown-6 molecule, the latter disposed about a centre of inversion. The tin atom is coordinated by three Cl atoms, that define a facial arrangement, a chelating...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983741/ https://www.ncbi.nlm.nih.gov/pubmed/21580253 http://dx.doi.org/10.1107/S1600536810005908 |
| _version_ | 1782191946423336960 |
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| author | Wardell, Solange M. S. V. Harrison, William T. A. Tiekink, Edward R. T. de Lima, Geraldo M. Wardell, James L. |
| author_facet | Wardell, Solange M. S. V. Harrison, William T. A. Tiekink, Edward R. T. de Lima, Geraldo M. Wardell, James L. |
| author_sort | Wardell, Solange M. S. V. |
| collection | PubMed |
| description | The asymmetric unit of the title compound, [Sn(C(3)H(6)NO)Cl(3)(H(2)O)](2)·C(12)H(24)O(6), comprises a six-coordinate tin complex and a 18-crown-6 molecule, the latter disposed about a centre of inversion. The tin atom is coordinated by three Cl atoms, that define a facial arrangement, a chelating C-,O- ligand, and a water molecule. The resulting CCl(3)O(2) donor set defines a distorted octahedral geometry. The tin-bound aqua ligand forms O—H⋯O hydrogen bonds to the centrosymmetric 18-crown-6 molecule, resulting in a tri-molecular aggregate. These assemble into a supramolecular chain along the a axis being connected by N—H⋯O hydrogen bonds. |
| format | Text |
| id | pubmed-2983741 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29837412010-12-30 fac-(2-Amidoethyl-κ(2) C (1),O)aquatrichloridotin(IV) 1,4,7,10,13,16-hexaoxacyclooctadecane (2/1) Wardell, Solange M. S. V. Harrison, William T. A. Tiekink, Edward R. T. de Lima, Geraldo M. Wardell, James L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Sn(C(3)H(6)NO)Cl(3)(H(2)O)](2)·C(12)H(24)O(6), comprises a six-coordinate tin complex and a 18-crown-6 molecule, the latter disposed about a centre of inversion. The tin atom is coordinated by three Cl atoms, that define a facial arrangement, a chelating C-,O- ligand, and a water molecule. The resulting CCl(3)O(2) donor set defines a distorted octahedral geometry. The tin-bound aqua ligand forms O—H⋯O hydrogen bonds to the centrosymmetric 18-crown-6 molecule, resulting in a tri-molecular aggregate. These assemble into a supramolecular chain along the a axis being connected by N—H⋯O hydrogen bonds. International Union of Crystallography 2010-02-20 /pmc/articles/PMC2983741/ /pubmed/21580253 http://dx.doi.org/10.1107/S1600536810005908 Text en © Wardell et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wardell, Solange M. S. V. Harrison, William T. A. Tiekink, Edward R. T. de Lima, Geraldo M. Wardell, James L. fac-(2-Amidoethyl-κ(2) C (1),O)aquatrichloridotin(IV) 1,4,7,10,13,16-hexaoxacyclooctadecane (2/1) |
| title |
fac-(2-Amidoethyl-κ(2)
C
(1),O)aquatrichloridotin(IV) 1,4,7,10,13,16-hexaoxacyclooctadecane (2/1) |
| title_full |
fac-(2-Amidoethyl-κ(2)
C
(1),O)aquatrichloridotin(IV) 1,4,7,10,13,16-hexaoxacyclooctadecane (2/1) |
| title_fullStr |
fac-(2-Amidoethyl-κ(2)
C
(1),O)aquatrichloridotin(IV) 1,4,7,10,13,16-hexaoxacyclooctadecane (2/1) |
| title_full_unstemmed |
fac-(2-Amidoethyl-κ(2)
C
(1),O)aquatrichloridotin(IV) 1,4,7,10,13,16-hexaoxacyclooctadecane (2/1) |
| title_short |
fac-(2-Amidoethyl-κ(2)
C
(1),O)aquatrichloridotin(IV) 1,4,7,10,13,16-hexaoxacyclooctadecane (2/1) |
| title_sort | fac-(2-amidoethyl-κ(2)
c
(1),o)aquatrichloridotin(iv) 1,4,7,10,13,16-hexaoxacyclooctadecane (2/1) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983741/ https://www.ncbi.nlm.nih.gov/pubmed/21580253 http://dx.doi.org/10.1107/S1600536810005908 |
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