Bis(2,6-diamino­pyridinium) hydrogen phthalate nitrate monohydrate

The title hydrated salt, 2C(5)H(8)N(3) (+)·C(8)H(5)O(4) (−)·NO(3) (−)·H(2)O, was obtained fortuitously from the reaction between 2,6-diamino­pyridine, phthalic acid and Co(NO(3))(2)·6H(2)O at 343 K. The asymmetric unit consists of two crystallographically independent 2,6-diamino­pyridinium cations,...

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Autores principales: Raissi Shabari, Akbar, Safaeimovahed, Maryam, Pourayoubi, Mehrdad
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983748/
https://www.ncbi.nlm.nih.gov/pubmed/21580321
http://dx.doi.org/10.1107/S1600536810004150
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author Raissi Shabari, Akbar
Safaeimovahed, Maryam
Pourayoubi, Mehrdad
author_facet Raissi Shabari, Akbar
Safaeimovahed, Maryam
Pourayoubi, Mehrdad
author_sort Raissi Shabari, Akbar
collection PubMed
description The title hydrated salt, 2C(5)H(8)N(3) (+)·C(8)H(5)O(4) (−)·NO(3) (−)·H(2)O, was obtained fortuitously from the reaction between 2,6-diamino­pyridine, phthalic acid and Co(NO(3))(2)·6H(2)O at 343 K. The asymmetric unit consists of two crystallographically independent 2,6-diamino­pyridinium cations, a hydrogen phthalate anion, a nitrate ion and a water mol­ecule of crystallization which in the crystal structure are linked by inter­molecular O—H⋯O and N—H⋯O hydrogen bonds into a three-dimensional network. In the hydrogen phthalate anion, there is a very strong intra­molecular O—H⋯O hydrogen bond.
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spelling pubmed-29837482010-12-30 Bis(2,6-diamino­pyridinium) hydrogen phthalate nitrate monohydrate Raissi Shabari, Akbar Safaeimovahed, Maryam Pourayoubi, Mehrdad Acta Crystallogr Sect E Struct Rep Online Organic Papers The title hydrated salt, 2C(5)H(8)N(3) (+)·C(8)H(5)O(4) (−)·NO(3) (−)·H(2)O, was obtained fortuitously from the reaction between 2,6-diamino­pyridine, phthalic acid and Co(NO(3))(2)·6H(2)O at 343 K. The asymmetric unit consists of two crystallographically independent 2,6-diamino­pyridinium cations, a hydrogen phthalate anion, a nitrate ion and a water mol­ecule of crystallization which in the crystal structure are linked by inter­molecular O—H⋯O and N—H⋯O hydrogen bonds into a three-dimensional network. In the hydrogen phthalate anion, there is a very strong intra­molecular O—H⋯O hydrogen bond. International Union of Crystallography 2010-02-06 /pmc/articles/PMC2983748/ /pubmed/21580321 http://dx.doi.org/10.1107/S1600536810004150 Text en © Raissi Shabari et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Raissi Shabari, Akbar
Safaeimovahed, Maryam
Pourayoubi, Mehrdad
Bis(2,6-diamino­pyridinium) hydrogen phthalate nitrate monohydrate
title Bis(2,6-diamino­pyridinium) hydrogen phthalate nitrate monohydrate
title_full Bis(2,6-diamino­pyridinium) hydrogen phthalate nitrate monohydrate
title_fullStr Bis(2,6-diamino­pyridinium) hydrogen phthalate nitrate monohydrate
title_full_unstemmed Bis(2,6-diamino­pyridinium) hydrogen phthalate nitrate monohydrate
title_short Bis(2,6-diamino­pyridinium) hydrogen phthalate nitrate monohydrate
title_sort bis(2,6-diamino­pyridinium) hydrogen phthalate nitrate monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983748/
https://www.ncbi.nlm.nih.gov/pubmed/21580321
http://dx.doi.org/10.1107/S1600536810004150
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