(R (P))-Menthyl (1-hydroxy­cyclo­hexyl)phenyl­phosphinate

The title compound, C(22)H(35)O(3)P, features a tetra­hedral P atom bonded to a phenyl ring, a hydroxy­cyclo­hexyl unit and the O atom of a menthyl group. The axial chirality at phospho­rus is R (P). In the crystal, mol­ecules are connected through O—H⋯O hydrogen bonds involving the hydr­oxy and P=O...

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Detalles Bibliográficos
Autores principales: Fu, Baoci, Zhao, Chang-Qiu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983758/
https://www.ncbi.nlm.nih.gov/pubmed/21580682
http://dx.doi.org/10.1107/S1600536810009219
Descripción
Sumario:The title compound, C(22)H(35)O(3)P, features a tetra­hedral P atom bonded to a phenyl ring, a hydroxy­cyclo­hexyl unit and the O atom of a menthyl group. The axial chirality at phospho­rus is R (P). In the crystal, mol­ecules are connected through O—H⋯O hydrogen bonds involving the hydr­oxy and P=O groups, forming chains along the 2(1) screw axis. The methyl groups of the isopropyl fragment in the menthyl unit are disordered over two sites of equal occupancy.

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