(R (P))-Menthyl (1-hydroxy­cyclo­hexyl)phenyl­phosphinate

The title compound, C(22)H(35)O(3)P, features a tetra­hedral P atom bonded to a phenyl ring, a hydroxy­cyclo­hexyl unit and the O atom of a menthyl group. The axial chirality at phospho­rus is R (P). In the crystal, mol­ecules are connected through O—H⋯O hydrogen bonds involving the hydr­oxy and P=O...

Descripción completa

Detalles Bibliográficos
Autores principales: Fu, Baoci, Zhao, Chang-Qiu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983758/
https://www.ncbi.nlm.nih.gov/pubmed/21580682
http://dx.doi.org/10.1107/S1600536810009219
_version_ 1782191950784364544
author Fu, Baoci
Zhao, Chang-Qiu
author_facet Fu, Baoci
Zhao, Chang-Qiu
author_sort Fu, Baoci
collection PubMed
description The title compound, C(22)H(35)O(3)P, features a tetra­hedral P atom bonded to a phenyl ring, a hydroxy­cyclo­hexyl unit and the O atom of a menthyl group. The axial chirality at phospho­rus is R (P). In the crystal, mol­ecules are connected through O—H⋯O hydrogen bonds involving the hydr­oxy and P=O groups, forming chains along the 2(1) screw axis. The methyl groups of the isopropyl fragment in the menthyl unit are disordered over two sites of equal occupancy.
format Text
id pubmed-2983758
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29837582010-12-30 (R (P))-Menthyl (1-hydroxy­cyclo­hexyl)phenyl­phosphinate Fu, Baoci Zhao, Chang-Qiu Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(22)H(35)O(3)P, features a tetra­hedral P atom bonded to a phenyl ring, a hydroxy­cyclo­hexyl unit and the O atom of a menthyl group. The axial chirality at phospho­rus is R (P). In the crystal, mol­ecules are connected through O—H⋯O hydrogen bonds involving the hydr­oxy and P=O groups, forming chains along the 2(1) screw axis. The methyl groups of the isopropyl fragment in the menthyl unit are disordered over two sites of equal occupancy. International Union of Crystallography 2010-03-17 /pmc/articles/PMC2983758/ /pubmed/21580682 http://dx.doi.org/10.1107/S1600536810009219 Text en © Fu and Zhao 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fu, Baoci
Zhao, Chang-Qiu
(R (P))-Menthyl (1-hydroxy­cyclo­hexyl)phenyl­phosphinate
title (R (P))-Menthyl (1-hydroxy­cyclo­hexyl)phenyl­phosphinate
title_full (R (P))-Menthyl (1-hydroxy­cyclo­hexyl)phenyl­phosphinate
title_fullStr (R (P))-Menthyl (1-hydroxy­cyclo­hexyl)phenyl­phosphinate
title_full_unstemmed (R (P))-Menthyl (1-hydroxy­cyclo­hexyl)phenyl­phosphinate
title_short (R (P))-Menthyl (1-hydroxy­cyclo­hexyl)phenyl­phosphinate
title_sort (r (p))-menthyl (1-hydroxy­cyclo­hexyl)phenyl­phosphinate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983758/
https://www.ncbi.nlm.nih.gov/pubmed/21580682
http://dx.doi.org/10.1107/S1600536810009219
work_keys_str_mv AT fubaoci rpmenthyl1hydroxycyclohexylphenylphosphinate
AT zhaochangqiu rpmenthyl1hydroxycyclohexylphenylphosphinate

Ejemplares similares