[(Z)-O-Isopropyl N-(m-tol­yl)thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I)

The Au atom in the title compound, [Au(C(11)H(14)NOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S—Au—P = 174.73 (3)°], with the distortion due in part to a close intra­molecular Au⋯O contact [3.060 (3) Å]. In the crystal structure, mol­e...

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Detalles Bibliográficos
Autores principales: Tadbuppa, Primjira P., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983763/
https://www.ncbi.nlm.nih.gov/pubmed/21580519
http://dx.doi.org/10.1107/S160053681000975X
Descripción
Sumario:The Au atom in the title compound, [Au(C(11)H(14)NOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S—Au—P = 174.73 (3)°], with the distortion due in part to a close intra­molecular Au⋯O contact [3.060 (3) Å]. In the crystal structure, mol­ecules are arranged in layers in the bc plane with the primary connections between the arrays being of the type C—H⋯π.

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