[(Z)-O-Isopropyl N-(m-tol­yl)thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I)

The Au atom in the title compound, [Au(C(11)H(14)NOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S—Au—P = 174.73 (3)°], with the distortion due in part to a close intra­molecular Au⋯O contact [3.060 (3) Å]. In the crystal structure, mol­e...

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Detalles Bibliográficos
Autores principales: Tadbuppa, Primjira P., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983763/
https://www.ncbi.nlm.nih.gov/pubmed/21580519
http://dx.doi.org/10.1107/S160053681000975X
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author Tadbuppa, Primjira P.
Tiekink, Edward R. T.
author_facet Tadbuppa, Primjira P.
Tiekink, Edward R. T.
author_sort Tadbuppa, Primjira P.
collection PubMed
description The Au atom in the title compound, [Au(C(11)H(14)NOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S—Au—P = 174.73 (3)°], with the distortion due in part to a close intra­molecular Au⋯O contact [3.060 (3) Å]. In the crystal structure, mol­ecules are arranged in layers in the bc plane with the primary connections between the arrays being of the type C—H⋯π.
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spelling pubmed-29837632010-12-30 [(Z)-O-Isopropyl N-(m-tol­yl)thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I) Tadbuppa, Primjira P. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Au atom in the title compound, [Au(C(11)H(14)NOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S—Au—P = 174.73 (3)°], with the distortion due in part to a close intra­molecular Au⋯O contact [3.060 (3) Å]. In the crystal structure, mol­ecules are arranged in layers in the bc plane with the primary connections between the arrays being of the type C—H⋯π. International Union of Crystallography 2010-03-20 /pmc/articles/PMC2983763/ /pubmed/21580519 http://dx.doi.org/10.1107/S160053681000975X Text en © Tadbuppa and Tiekink 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tadbuppa, Primjira P.
Tiekink, Edward R. T.
[(Z)-O-Isopropyl N-(m-tol­yl)thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I)
title [(Z)-O-Isopropyl N-(m-tol­yl)thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I)
title_full [(Z)-O-Isopropyl N-(m-tol­yl)thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I)
title_fullStr [(Z)-O-Isopropyl N-(m-tol­yl)thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I)
title_full_unstemmed [(Z)-O-Isopropyl N-(m-tol­yl)thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I)
title_short [(Z)-O-Isopropyl N-(m-tol­yl)thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I)
title_sort [(z)-o-isopropyl n-(m-tol­yl)thio­carbamato-κs](tricyclo­hexyl­phosphine-κp)gold(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983763/
https://www.ncbi.nlm.nih.gov/pubmed/21580519
http://dx.doi.org/10.1107/S160053681000975X
work_keys_str_mv AT tadbuppaprimjirap zoisopropylnmtolylthiocarbamatokstricyclohexylphosphinekpgoldi
AT tiekinkedwardrt zoisopropylnmtolylthiocarbamatokstricyclohexylphosphinekpgoldi

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