Poly[(dimethyl­formamide)(μ(4)-2,2′-sulfanediyldibenzoato)nickel(II)]

The title centrosymmetric dinuclear Ni(II) complex, [Ni(C(14)H(8)O(4)S)(C(3)H(7)NO)](n), was prepared via reaction of Ni(NO(3))(2)·6H(2)O and thio­salicylic acid, with H(2)O and dimethyl­formamide (DMF) as the mixed solvent. The central Ni(II) ion is five-coordinated by five O atoms from DMF and fro...

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Detalles Bibliográficos
Autor principal: Xie, Jiang-Bo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983770/
https://www.ncbi.nlm.nih.gov/pubmed/21580481
http://dx.doi.org/10.1107/S1600536810007749
Descripción
Sumario:The title centrosymmetric dinuclear Ni(II) complex, [Ni(C(14)H(8)O(4)S)(C(3)H(7)NO)](n), was prepared via reaction of Ni(NO(3))(2)·6H(2)O and thio­salicylic acid, with H(2)O and dimethyl­formamide (DMF) as the mixed solvent. The central Ni(II) ion is five-coordinated by five O atoms from DMF and from the carboxyl­ate groups of the organic ligand. The symmetry-related coordination polyhedra inter­link into centrosymmetric dimeric units and these, in turn, are linked into infinite chains propagating parallel to [100].

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