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Poly[(dimethylformamide)(μ(4)-2,2′-sulfanediyldibenzoato)nickel(II)]
The title centrosymmetric dinuclear Ni(II) complex, [Ni(C(14)H(8)O(4)S)(C(3)H(7)NO)](n), was prepared via reaction of Ni(NO(3))(2)·6H(2)O and thiosalicylic acid, with H(2)O and dimethylformamide (DMF) as the mixed solvent. The central Ni(II) ion is five-coordinated by five O atoms from DMF and fro...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983770/ https://www.ncbi.nlm.nih.gov/pubmed/21580481 http://dx.doi.org/10.1107/S1600536810007749 |
| _version_ | 1782191953602936832 |
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| author | Xie, Jiang-Bo |
| author_facet | Xie, Jiang-Bo |
| author_sort | Xie, Jiang-Bo |
| collection | PubMed |
| description | The title centrosymmetric dinuclear Ni(II) complex, [Ni(C(14)H(8)O(4)S)(C(3)H(7)NO)](n), was prepared via reaction of Ni(NO(3))(2)·6H(2)O and thiosalicylic acid, with H(2)O and dimethylformamide (DMF) as the mixed solvent. The central Ni(II) ion is five-coordinated by five O atoms from DMF and from the carboxylate groups of the organic ligand. The symmetry-related coordination polyhedra interlink into centrosymmetric dimeric units and these, in turn, are linked into infinite chains propagating parallel to [100]. |
| format | Text |
| id | pubmed-2983770 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29837702010-12-30 Poly[(dimethylformamide)(μ(4)-2,2′-sulfanediyldibenzoato)nickel(II)] Xie, Jiang-Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title centrosymmetric dinuclear Ni(II) complex, [Ni(C(14)H(8)O(4)S)(C(3)H(7)NO)](n), was prepared via reaction of Ni(NO(3))(2)·6H(2)O and thiosalicylic acid, with H(2)O and dimethylformamide (DMF) as the mixed solvent. The central Ni(II) ion is five-coordinated by five O atoms from DMF and from the carboxylate groups of the organic ligand. The symmetry-related coordination polyhedra interlink into centrosymmetric dimeric units and these, in turn, are linked into infinite chains propagating parallel to [100]. International Union of Crystallography 2010-03-06 /pmc/articles/PMC2983770/ /pubmed/21580481 http://dx.doi.org/10.1107/S1600536810007749 Text en © Jiang-Bo Xie 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Xie, Jiang-Bo Poly[(dimethylformamide)(μ(4)-2,2′-sulfanediyldibenzoato)nickel(II)] |
| title | Poly[(dimethylformamide)(μ(4)-2,2′-sulfanediyldibenzoato)nickel(II)] |
| title_full | Poly[(dimethylformamide)(μ(4)-2,2′-sulfanediyldibenzoato)nickel(II)] |
| title_fullStr | Poly[(dimethylformamide)(μ(4)-2,2′-sulfanediyldibenzoato)nickel(II)] |
| title_full_unstemmed | Poly[(dimethylformamide)(μ(4)-2,2′-sulfanediyldibenzoato)nickel(II)] |
| title_short | Poly[(dimethylformamide)(μ(4)-2,2′-sulfanediyldibenzoato)nickel(II)] |
| title_sort | poly[(dimethylformamide)(μ(4)-2,2′-sulfanediyldibenzoato)nickel(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983770/ https://www.ncbi.nlm.nih.gov/pubmed/21580481 http://dx.doi.org/10.1107/S1600536810007749 |
| work_keys_str_mv | AT xiejiangbo polydimethylformamidem422sulfanediyldibenzoatonickelii |