(2-{[1,1-Bis(hydroxy­meth­yl)-2-oxidoeth­yl]imino­meth­yl}-4-chloro­phenolato-κ(3) N,O,O′)dibutyl­tin(IV)

The Schiff base ligand in the title compound, [Sn(C(4)H(9))(2)(C(11)H(12)ClNO(4))], chelates to the Sn atom through the two deprotonated O atoms, as well as through the N atom, to confer an overall cis-C(2)SnNO(2) trigonal-bipyramidal geometry at tin [C—Sn—C = 130.3 (1)°]. The hydr­oxy groups engage...

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Detalles Bibliográficos
Autores principales: Reisi, Reza, Misran, Misni, Lo, Kong Mun, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983778/
https://www.ncbi.nlm.nih.gov/pubmed/21580562
http://dx.doi.org/10.1107/S1600536810011384
Descripción
Sumario:The Schiff base ligand in the title compound, [Sn(C(4)H(9))(2)(C(11)H(12)ClNO(4))], chelates to the Sn atom through the two deprotonated O atoms, as well as through the N atom, to confer an overall cis-C(2)SnNO(2) trigonal-bipyramidal geometry at tin [C—Sn—C = 130.3 (1)°]. The hydr­oxy groups engage in O—H⋯O hydrogen bonding with the O atoms of adjacent mol­ecules, generating a chain running along the c axis.

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