(2-{[1,1-Bis(hydroxy­meth­yl)-2-oxidoeth­yl]imino­meth­yl}-4-chloro­phenolato-κ(3) N,O,O′)dibutyl­tin(IV)

The Schiff base ligand in the title compound, [Sn(C(4)H(9))(2)(C(11)H(12)ClNO(4))], chelates to the Sn atom through the two deprotonated O atoms, as well as through the N atom, to confer an overall cis-C(2)SnNO(2) trigonal-bipyramidal geometry at tin [C—Sn—C = 130.3 (1)°]. The hydr­oxy groups engage...

Descripción completa

Detalles Bibliográficos
Autores principales: Reisi, Reza, Misran, Misni, Lo, Kong Mun, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983778/
https://www.ncbi.nlm.nih.gov/pubmed/21580562
http://dx.doi.org/10.1107/S1600536810011384
_version_ 1782191955565871104
author Reisi, Reza
Misran, Misni
Lo, Kong Mun
Ng, Seik Weng
author_facet Reisi, Reza
Misran, Misni
Lo, Kong Mun
Ng, Seik Weng
author_sort Reisi, Reza
collection PubMed
description The Schiff base ligand in the title compound, [Sn(C(4)H(9))(2)(C(11)H(12)ClNO(4))], chelates to the Sn atom through the two deprotonated O atoms, as well as through the N atom, to confer an overall cis-C(2)SnNO(2) trigonal-bipyramidal geometry at tin [C—Sn—C = 130.3 (1)°]. The hydr­oxy groups engage in O—H⋯O hydrogen bonding with the O atoms of adjacent mol­ecules, generating a chain running along the c axis.
format Text
id pubmed-2983778
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29837782010-12-30 (2-{[1,1-Bis(hydroxy­meth­yl)-2-oxidoeth­yl]imino­meth­yl}-4-chloro­phenolato-κ(3) N,O,O′)dibutyl­tin(IV) Reisi, Reza Misran, Misni Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Schiff base ligand in the title compound, [Sn(C(4)H(9))(2)(C(11)H(12)ClNO(4))], chelates to the Sn atom through the two deprotonated O atoms, as well as through the N atom, to confer an overall cis-C(2)SnNO(2) trigonal-bipyramidal geometry at tin [C—Sn—C = 130.3 (1)°]. The hydr­oxy groups engage in O—H⋯O hydrogen bonding with the O atoms of adjacent mol­ecules, generating a chain running along the c axis. International Union of Crystallography 2010-03-31 /pmc/articles/PMC2983778/ /pubmed/21580562 http://dx.doi.org/10.1107/S1600536810011384 Text en © Reisi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Reisi, Reza
Misran, Misni
Lo, Kong Mun
Ng, Seik Weng
(2-{[1,1-Bis(hydroxy­meth­yl)-2-oxidoeth­yl]imino­meth­yl}-4-chloro­phenolato-κ(3) N,O,O′)dibutyl­tin(IV)
title (2-{[1,1-Bis(hydroxy­meth­yl)-2-oxidoeth­yl]imino­meth­yl}-4-chloro­phenolato-κ(3) N,O,O′)dibutyl­tin(IV)
title_full (2-{[1,1-Bis(hydroxy­meth­yl)-2-oxidoeth­yl]imino­meth­yl}-4-chloro­phenolato-κ(3) N,O,O′)dibutyl­tin(IV)
title_fullStr (2-{[1,1-Bis(hydroxy­meth­yl)-2-oxidoeth­yl]imino­meth­yl}-4-chloro­phenolato-κ(3) N,O,O′)dibutyl­tin(IV)
title_full_unstemmed (2-{[1,1-Bis(hydroxy­meth­yl)-2-oxidoeth­yl]imino­meth­yl}-4-chloro­phenolato-κ(3) N,O,O′)dibutyl­tin(IV)
title_short (2-{[1,1-Bis(hydroxy­meth­yl)-2-oxidoeth­yl]imino­meth­yl}-4-chloro­phenolato-κ(3) N,O,O′)dibutyl­tin(IV)
title_sort (2-{[1,1-bis(hydroxy­meth­yl)-2-oxidoeth­yl]imino­meth­yl}-4-chloro­phenolato-κ(3) n,o,o′)dibutyl­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983778/
https://www.ncbi.nlm.nih.gov/pubmed/21580562
http://dx.doi.org/10.1107/S1600536810011384
work_keys_str_mv AT reisireza 211bishydroxymethyl2oxidoethyliminomethyl4chlorophenolatok3noodibutyltiniv
AT misranmisni 211bishydroxymethyl2oxidoethyliminomethyl4chlorophenolatok3noodibutyltiniv
AT lokongmun 211bishydroxymethyl2oxidoethyliminomethyl4chlorophenolatok3noodibutyltiniv
AT ngseikweng 211bishydroxymethyl2oxidoethyliminomethyl4chlorophenolatok3noodibutyltiniv

Ejemplares similares